The DOI matches its Crossref record; 16 of the 16 references it cites were found in a registry or an index.
Probing the 3d Spin Momentum with X-ray Emission Spectroscopy: The Case of Molecular-Spin Transitions
Open accessAbstract
We report X-ray emission spectra of Fe(III), Fe(II), and Co(II) spin-crossover compounds in their high-spin and low-spin forms. It is shown that all X-ray emission features are sensitive to the spin state. Variations of the Kbeta and the Kalpha emission line shapes, which are in agreement with theory, can be used as quantitative probes of the spin state; it is suggested that with appropriate reference experiments one can extract the spin momentum for a general case. Resonant X-ray emission spectra unveil details of the redistribution of electrons on the 3d levels associated with the spin-state change by revealing features at the X-ray absorption preedge not accessible through standard absorption measurements.
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Cites
A Multiplet Analysis of Fe K-Edge 1s → 3d Pre-Edge Features of Iron Complexes
Westre, T. E., Kennepohl, P., DeWitt, J. G., Hedman, B., Hodgson, K. O., & Solomon, E. I. (1997) · Journal of the American Chemical Society · doi:10.1021/ja964352a · Cited by 1,473
Glatzel, P., & Bergmann, U. (2005) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.04.011 · Cited by 972
Elimination of the inner-shell lifetime broadening in x-ray-absorption spectroscopy
Hämäläinen, K., Siddons, D. P., Hastings, J. B., & Berman, L. E. (1991) · Physical Review Letters · doi:10.1103/physrevlett.67.2850 · Cited by 557
Structure and Flexibility Adaptation in Nonspecific and Specific Protein-DNA Complexes
Kalodimos, C. G., Biris, N., Bonvin, A. M. J. J., Levandoski, M. M., Guennuegues, M., Boelens, R., & Kaptein, R. (2004) · Science · doi:10.1126/science.1097064 · Cited by 543
Electronic Transitions in Perovskite: Possible Nonconvecting Layers in the Lower Mantle
Badro, J., Rueff, J.-P., Vankó, G., Monaco, G., Fiquet, G., & Guyot, F. (2004) · Science · doi:10.1126/science.1098840 · Cited by 373
X-ray MnKβemission spectra of manganese oxides and manganates
Tsutsumi, K., Nakamori, H., & Ichikawa, K. (1976) · Physical Review B · doi:10.1103/physrevb.13.929 · Cited by 199
Temperature- and pressure-induced spin-state transitions inLaCoO3
Vankó, G., Rueff, J.-P., Mattila, A., Németh, Z., & Shukla, A. (2006) · Physical Review B · doi:10.1103/physrevb.73.024424 · Cited by 196
Self-citationX-Ray Spectra and Chemical Binding
MEISEL, A., LEONHARDT, G., & Szargan, R. (1989) · Springer series in chemical physics · doi:10.1007/978-3-642-82262-9 · Cited by 162
van der Laan, G., Thole, B. T., Sawatzky, G. A., & Verdaguer, M. (1988) · Physical review. B, Condensed matter · doi:10.1103/physrevb.37.6587 · Cited by 154
X-Ray spectra and chemical binding
(1991) · Applied Physics B · doi:10.1007/bf00325398 · Cited by 133
Cited by
Molecular spin crossover phenomenon: recent achievements and prospects
Bousseksou, A., Molnár, G., Salmon, L., & Nicolazzi, W. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15042a · Cited by 1,379
Self-citation(2020) · doi:10.1038/s41929-020-00545-2 · Cited by 741
Biasin, E., van Driel, T. B., Kjær, K. S., Dohn, A. O., Christensen, M., Harlang, T., Chabera, P., Liu, Y., Uhlig, J., Pápai, M., et al. (2016) · Physical Review Letters · doi:10.1103/physrevlett.117.013002 · Cited by 108
Self-citationSaveleva, V. A., Ebner, K., Ni, L., Smolentsev, G., Klose, D., Zitolo, A., Marelli, E., Li, J., Medarde, M., Safonova, O. V., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202016951 · Cited by 82
Kantor, I. Y., Dubrovinsky, L. S., & McCammon, C. A. (2006) · Physical Review B · doi:10.1103/physrevb.73.100101 · Cited by 72
Metadata
- Authors
- Vankó, G., Neisius, T., Molnár, G., Renz, F., Kárpáti, S., Shukla, A., & de Groot, F. M. F.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-05-27
- Volume
- 110
- Issue
- 24
- Pages
- 11647-11653
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2122321283
- Cited by
- 320
- References
- 16
- FWCI
- 7.48
- Type
- journal article
- Language
- en
- Open access
- green
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- Vankó, G., Neisius, T., Molnár, G., Renz, F., Kárpáti, S., Shukla, A., & de Groot, F. M. F. (2006). Probing the 3d Spin Momentum with X-ray Emission Spectroscopy: The Case of Molecular-Spin Transitions. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp0615961
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