The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Application of Hole Theory to Define Ionic Liquids by their Transport Properties
Abstract
Eutectic mixtures of quaternary ammonium salts with Lewis or Brønsted acids have been described as ionic liquid, but doubt exists over the compositional range for which this description is valid. In the current work, the conductivity, viscosity, density, and surface tension of a number of glycolic mixtures with choline chloride are measured over the mole fraction range 0 to 0.33. The data are fitted to hole theory, and it is proposed that the composition at which the measured conductivity matches the theoretical value is the point at which hole mobility becomes the dominant mechanism for charge mobility. For the mixtures of ethylene glycol and butanediol, this occurs at a ChCl mole fraction of approximately 0.2.
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Citations
Cites
Ionic liquids: solvent properties and organic reactivity
Chiappe, C., & Pieraccini, D. (2005) · Journal of Physical Organic Chemistry · doi:10.1002/poc.863 · Cited by 1,169
Cited by
Deep Eutectic Solvents (DESs) and Their Applications
Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378
Self-citationDeep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Deep Eutectic Solvents: Physicochemical Properties and Gas Separation Applications
García, G., Aparicio, S., Ullah, R., & Atilhan, M. (2015) · Energy & Fuels · doi:10.1021/ef5028873 · Cited by 1,112
Basics and properties of deep eutectic solvents: a review
El Achkar, T., Greige-Gerges, H., & Fourmentin, S. (2021) · Environmental Chemistry Letters · doi:10.1007/s10311-021-01225-8 · Cited by 1,106
Florindo, C., Oliveira, F. S., Rebelo, L. P. N., Fernandes, A. M., & Marrucho, I. M. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc500439w · Cited by 977
Metadata
- Authors
- Abbott, A. P., Harris, R. C., & Ryder, K. S.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-03-10
- Volume
- 111
- Issue
- 18
- Pages
- 4910-4913
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1973869966
- Cited by
- 556
- References
- 1
- FWCI
- 3.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- Abbott, A. P., Harris, R. C., & Ryder, K. S. (2007). Application of Hole Theory to Define Ionic Liquids by their Transport Properties. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp0671998
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
