The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Screening Metal−Organic Framework Materials for Membrane-based Methane/Carbon Dioxide Separations
Open accessAbstract
High Resolution Image Download MS PowerPoint Slide Metal−organic frameworks (MOF) are a diverse family of highly porous materials that have potential advantages as adsorbents and membranes for gas separations. Because the fabrication of membranes from crystalline materials is challenging, nothing is currently known about what advantages MOFs may have over more conventional materials for membrane-based separations. We use atomically detailed simulations to present the first information about the performance of MOFs as membranes for gas separations using the separation of CO 2 /CH 4 mixtures by MOF-5 as an example. Describing membrane performance requires information about both mixture adsorption and mixture diffusion in the membrane material. Our results show that mixture effects play a crucial role in determining the performance of MOF-5 membranes under conditions relevant for natural-gas applications, indicating that modeling or experimental studies that examine only single-component gases will be insufficient to understand the properties of MOF-based membranes in practical applications.
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Citations
Cites
Improved SAPO‐34 Membranes for CO2/CH4 Separations
Li, S., Falconer, J. L., & Noble, R. D. (2006) · Advanced Materials · doi:10.1002/adma.200601147 · Cited by 283
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Carbon Dioxide Capture: Prospects for New Materials
D'Alessandro, D. M., Smit, B., & Long, J. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000431 · Cited by 4,046
CO2 Capture and Separations Using MOFs: Computational and Experimental Studies
Yu, J., Xie, L.-H., Li, J.-R., Ma, Y., Seminario, J. M., & Balbuena, P. B. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00626 · Cited by 1,047
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
Couck, S., Denayer, J. F. M., Baron, G. V., Rémy, T., Gascon, J., & Kapteijn, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900555r · Cited by 988
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Biomedical Applications of Metal Organic Frameworks
Keskin, S., & Kızılel, S. (2011) · Industrial & Engineering Chemistry Research · doi:10.1021/ie101312k · Cited by 607
Self-citationBig-Data Science in Porous Materials: Materials Genomics and Machine Learning
Jablonka, K. M., Ongari, D., Moosavi, S. M., & Smit, B. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00004 · Cited by 599
Du, C., Zhang, Z., Yu, G., Wu, H., Chen, H., Zhou, L., Zhang, Y., Su, Y., Tan, S., Yang, L., et al. (2021) · Chemosphere · doi:10.1016/j.chemosphere.2020.129501 · Cited by 543
Keskin, S., Liu, J., Rankin, R. B., Johnson, J. K., & Sholl, D. S. (2009) · Industrial & Engineering Chemistry Research · doi:10.1021/ie800666s · Cited by 310
Self-citationLiu, B., & Smit, B. (2009) · Langmuir · doi:10.1021/la900823d · Cited by 302
CO2 Capture from Dilute Gases as a Component of Modern Global Carbon Management
Jones, C. W. (2011) · Annual Review of Chemical and Biomolecular Engineering · doi:10.1146/annurev-chembioeng-061010-114252 · Cited by 268
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Metadata
- Authors
- Keskin, S., & Sholl, D. S.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-08-31
- Volume
- 111
- Issue
- 38
- Pages
- 14055-14059
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2069945445
- Cited by
- 202
- References
- 1
- FWCI
- 51.41
- Type
- journal article
- Language
- en
- Open access
- bronze
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