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Synthesis and Enhanced Visible-Light Photoelectrocatalytic Activity of p−n Junction BiOI/TiO2Nanotube Arrays

Dai, Gaopeng, Yu, Jiaguo, Liu, Gang·2011·The Journal of Physical Chemistry C

Abstract

p − n junction BiOI/TiO 2 nanotube arrays (NTs) were prepared by coating BiOI on the tube wall of the self-organized TiO 2 NTs using a novel impregnating−hydroxylation method. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and UV−vis absorption spectroscopy. The photoelectrocatalytic (PEC) activity toward degradation of methyl orange (MO) aqueous solutions under visible-light irradiation (λ > 420 nm) by p − n junction BiOI/TiO 2 NTs was investigated. The results from the current study demonstrate that the as-prepared BiOI/TiO 2 junction NTs display much greater PEC activity than the respective pure BiOI and TiO 2 counterparts due to the synergetic effects of several factors including the strong visible absorption, the formation of p − n junction, and the impact of external electrostatic field. The proposed mechanism responsible for the enhanced performance was further confirmed by the transient photocurrent response experiments.

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Metadata

Authors
Dai, G., Yu, J., & Liu, G.
Venue
The Journal of Physical Chemistry C
Published
2011-03-25
Volume
115
Issue
15
Pages
7339-7346
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2079151014
Cited by
524
References
2
FWCI
19.57
Type
journal article
Language
en
Open access
closed

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