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Enhanced Thermal Conductivity in a Nanostructured Phase Change Composite due to Low Concentration Graphene Additives
Abstract
Abstract The liquid−solid phase change enthalpy, crystallization, and thermal conductivity of graphene/1-octadecanol (stearyl alcohol) composite, a nanostructured phase change material, was investigated as a function of graphene content. The thermal conductivity (κ) of the nanocomposite increased by nearly 2.5-fold (∼140% increase) upon ∼4% (by weight) graphene addition while the drop in the heat of fusion (i.e., storage capacity) was only ∼15.4%. The enhancement in thermal properties of 1-octadecanol obtained with the addition of graphene is markedly superior to the effect of other nanofillers such as silver nanowires and carbon nanotubes reported previously in the literature. Boosting the thermal conductivity of organic phase change materials without incurring a significant loss in the heat of fusion is one of the key issues in enabling their practical application as latent heat storage/release units for thermal management and thermal protection.
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Cites
Superior Thermal Conductivity of Single-Layer Graphene
Balandin, A. A., Ghosh, S., Bao, W., Calizo, I., Teweldebrhan, D., Miao, F., & Lau, C. N. (2008) · Nano Letters · doi:10.1021/nl0731872 · Cited by 13,823
Thermal conductivity enhancement of Ag nanowires on an organic phase change material
Zeng, J. L., Cao, Z., Yang, D. W., Sun, L. X., & Zhang, L. (2010) · Journal of Thermal Analysis and Calorimetry · doi:10.1007/s10973-009-0472-y · Cited by 281
Cited by
Emerging challenges and materials for thermal management of electronics
Moore, A. L., & Shi, L. (2014) · Materials Today · doi:10.1016/j.mattod.2014.04.003 · Cited by 2,106
Sharma, R. K., Ganesan, P., Tyagi, V. V., Metselaar, H. S. C., & Sandaran, S. C. (2015) · Energy Conversion and Management · doi:10.1016/j.enconman.2015.01.084 · Cited by 809
Huang, X., Chen, X., Li, A., Atinafu, D., Gao, H., Dong, W., & Wang, G. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.09.013 · Cited by 701
Ji, H., Sellan, D. P., Pettes, M. T., Kong, X., Ji, J., Shi, L., & Ruoff, R. S. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42573h · Cited by 592
Zhang, P., Xiao, X., & Ma, Z. W. (2016) · Applied Energy · doi:10.1016/j.apenergy.2015.12.043 · Cited by 555
Metadata
- Authors
- Yavari, F., Fard, H. R., Pashayi, K., Reif, J., Zamiri, A., Yu, Z., Ozisik, R., Borca-Tasciuc, T., & Koratkar, N.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-04-11
- Volume
- 115
- Issue
- 17
- Pages
- 8753-8758
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2326524880
- Cited by
- 450
- References
- 2
- FWCI
- 46.67
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yavari, F., Fard, H. R., Pashayi, K., Reif, J., Zamiri, A., Yu, Z., Ozisik, R., Borca-Tasciuc, T., & Koratkar, N. (2011). Enhanced Thermal Conductivity in a Nanostructured Phase Change Composite due to Low Concentration Graphene Additives. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp200838s
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