Cited by 15Spectroscopy and Quantum Chemical StudiesPhotochemistry and Electron Transfer StudiesLaser-Matter Interactions and Applications

Studies of Impulsive Vibrational Influence on Ultrafast Electronic Excitation Transfer

Biggs, Jason D., Cina, Jeffrey A.·2012·The Journal of Physical Chemistry A

Abstract

We investigated electronic energy-transfer dynamics in three model dimers within which coherent intramonomer nuclear motion had been induced by impulsive Raman excitation using an optimized, electronically preresonant control pulse. Calculations of the donor-survival probability, the ultrafast pump-probe signal, and the pump-probe difference signal are presented for dithia-anthracenophane and homodimers of 2-difluoromethylanthracene and 2-trifluoromethylanthracene. Survival probabilities and signals, along with phase-space analyses, elucidated the mechanisms, extent, and spectroscopic manifestations of external vibrational or torsional control over electronic excitation transfer.

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Crossref · 10.1021/jp2094609

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56 of 56 references verified0 citation errors · 0 not checkable

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  • There is compelling theoretical and/or experimental evidence that quantum phenomena are essential for understanding the mechanism underlying olfaction.

    “environment assisted excitation energy transport in photosynthesis [11, 15, 16], magneto-reception of birds [17-19] and the mechanism underlying olfaction [20, 21], for which there is some compelling theoretical and/or experimental evidence that quantum phenomena are essential for their understanding.”

    From Vibrations, quanta and biology (2013) · cites this paper as [20]

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Authors
Biggs, J. D., & Cina, J. A.
Affiliations
University of Oregon (US)
Corresponding author
Cina, Jeffrey A.
Venue
The Journal of Physical Chemistry A
Published
2012-02-10
Volume
116
Issue
7
Pages
1683-1693
ISSN
  • 1089-5639 (ISSN-L)
  • 1520-5215
OpenAlex
W2319474040
Cited by
15
References
56
Citations by year
2024: 1 · 2023: 1 · 2020: 2 · 2017: 1 · 2016: 2 · 2015: 1 · 2014: 3 · 2013: 1 · 2012: 3
FWCI
1.32
Type
journal article
Language
en
Open access
closed
Locations
  • The Journal of Physical Chemistry A (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
  • Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Laser-Matter Interactions and Applications
Keywords
excitation energy transfer, ultrafast dynamics, coherent control, pump-probe spectroscopy, dimers, vibration control, phase space analysis

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