Studies of Impulsive Vibrational Influence on Ultrafast Electronic Excitation Transfer
Abstract
We investigated electronic energy-transfer dynamics in three model dimers within which coherent intramonomer nuclear motion had been induced by impulsive Raman excitation using an optimized, electronically preresonant control pulse. Calculations of the donor-survival probability, the ultrafast pump-probe signal, and the pump-probe difference signal are presented for dithia-anthracenophane and homodimers of 2-difluoromethylanthracene and 2-trifluoromethylanthracene. Survival probabilities and signals, along with phase-space analyses, elucidated the mechanisms, extent, and spectroscopic manifestations of external vibrational or torsional control over electronic excitation transfer.
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There is compelling theoretical and/or experimental evidence that quantum phenomena are essential for understanding the mechanism underlying olfaction.
“environment assisted excitation energy transport in photosynthesis [11, 15, 16], magneto-reception of birds [17-19] and the mechanism underlying olfaction [20, 21], for which there is some compelling theoretical and/or experimental evidence that quantum phenomena are essential for their understanding.”
From Vibrations, quanta and biology (2013) · cites this paper as [20]
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Vibrations, quanta and biology
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- Authors
- Biggs, J. D., & Cina, J. A.
- Affiliations
- University of Oregon (US)
- Corresponding author
- Cina, Jeffrey A.
- ORCID
- Cina, Jeffrey A.
- Venue
- The Journal of Physical Chemistry A
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-02-10
- Volume
- 116
- Issue
- 7
- Pages
- 1683-1693
- ISSN
- 1089-5639 (ISSN-L)
- 1520-5215
- OpenAlex
- W2319474040
- Cited by
- 15
- References
- 56
- Citations by year
- 2024: 1 · 2023: 1 · 2020: 2 · 2017: 1 · 2016: 2 · 2015: 1 · 2014: 3 · 2013: 1 · 2012: 3
- FWCI
- 1.32
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Physical Chemistry A (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Laser-Matter Interactions and Applications
- Keywords
- excitation energy transfer, ultrafast dynamics, coherent control, pump-probe spectroscopy, dimers, vibration control, phase space analysis
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