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Raman and Infrared Spectroscopy of α and β Phases of Thin Nickel Hydroxide Films Electrochemically Formed on Nickel

Hall, David S., Lockwood, David J., Poirier, Shawn, Bock, Christina, MacDougall, Barry R.·2012·The Journal of Physical Chemistry A
DOI 10.1021/jp303546r
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Abstract

The present work utilizes Raman and infrared (IR) spectroscopy, supported by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) to re-examine the fine structural details of Ni(OH)(2), which is a key material in many energy-related applications. This work also unifies the large body of literature on the topic. Samples were prepared by the galvanostatic basification of nickel salts and by aging the deposits in hot KOH solutions. A simplified model is presented consisting of two fundamental phases (α and β) of Ni(OH)(2) and a range of possible structural disorder arising from factors such as impurities, hydration, and crystal defects. For the first time, all of the lattice modes of β-Ni(OH)(2) have been identified and assigned using factor group analysis. Ni(OH)(2) films can be rapidly identified in pure and mixed samples using Raman or IR spectroscopy by measuring their strong O-H stretching modes, which act as fingerprints. Thus, this work establishes methods to measure the phase, or phases, and disorder at a Ni(OH)(2) sample surface and to correlate desired chemical properties to their structural origins.

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Metadata

Authors
Hall, D. S., Lockwood, D. J., Poirier, S., Bock, C., & MacDougall, B. R.
Venue
The Journal of Physical Chemistry A
Publisher
American Chemical Society (ACS)
Published
2012-06-15
Volume
116
Issue
25
Pages
6771-6784
ISSN
  • 1089-5639 (ISSN-L)
  • 1520-5215
DOI
10.1021/jp303546r
OpenAlex
W2023534334
Cited by
445
References
0
FWCI
3.16
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Raman and Infrared Spectroscopy of α and β Phases of Thin Nickel Hydroxide Films Electrochemically Formed on Nickel. https://app.cochat.ai/papers/10.1021/jp303546r
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Hall, D. S., Lockwood, D. J., Poirier, S., Bock, C., & MacDougall, B. R. (2012). Raman and Infrared Spectroscopy of α and β Phases of Thin Nickel Hydroxide Films Electrochemically Formed on Nickel. The Journal of Physical Chemistry A. https://doi.org/10.1021/jp303546r

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