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Insights into Adsorption of NH3 on HKUST-1 Metal–Organic Framework: A Multitechnique Approach
Open accessAbstract
We report a careful characterization of the interaction of NH 3 with the Cu(II) sites of the [Cu 2 C 4 O 8 ] paddle-wheel cornerstone of the HKUST-1 metallorganic framework, also known as Cu 3 (BTC) 2 . The general picture emerging from combining XRPD, EXAFS, XANES, mid- and far-IR, DRUV–vis, and EPR techniques is that the presence of traces of water has relevant consequences on the effect of ammonia on the MOF framework. NH 3 adsorption on the dry system results in a strong chemisorption on Cu(II) sites that distorts the framework, keeping the crystallinity of the material. Perturbation observed upon NH 3 adsorption is analogous to that observed for H 2 O, but noticeably enhanced. When the adsorption of ammonia occurs in humid conditions, a time-dependent, much deeper modification of the system is observed by all of the considered techniques. On a methodological ground, it is worth noticing that we used the optimization of XANES spectra to validate the bond distance obtained by EXAFS.
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Metal-organic framework materials as catalysts
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Metal-organic frameworks with high capacity and selectivity for harmful gases
Britt, D., Tranchemontagne, D., & Yaghi, O. M. (2008) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0804900105 · Cited by 958
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Metadata
- Authors
- Borfecchia, E., Maurelli, S., Gianolio, D., Groppo, E., Chiesa, M., Bonino, F., & Lamberti, C.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-09-10
- Volume
- 116
- Issue
- 37
- Pages
- 19839-19850
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2316605407
- Cited by
- 216
- References
- 2
- FWCI
- 7.34
- Type
- journal article
- Language
- en
- Open access
- green
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- Borfecchia, E., Maurelli, S., Gianolio, D., Groppo, E., Chiesa, M., Bonino, F., & Lamberti, C. (2012). Insights into Adsorption of NH3 on HKUST-1 Metal–Organic Framework: A Multitechnique Approach. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp305756k
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