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Cited by 353

The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.

Structural Changes of Cobalt-Based Perovskites upon Water Oxidation Investigated by EXAFS

Risch, Marcel, Grimaud, Alexis, May, Kevin J., Stoerzinger, Kelsey A., Chen, Tina J., Mansour, Azzam N., Shao-Horn, Yang·2013·The Journal of Physical Chemistry C

Abstract

While many perovskites remain crystalline during the oxygen evolution reaction (OER) in alkaline media, some highly active perovskites become amorphous. We studied the local structure changes of perovskites LaCoO 3, Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3-δ, and SrCo 0.8 Fe 0.2 O 3-δ before and after OER by X-ray absorption spectroscopy. No change in either local structure or OER activity was observed for LaCoO 3, while considerably enhanced OER activities and the conversion of the local structure from corner-sharing octahedra to edge-sharing octahedra were noted for Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3-δ and SrCo 0.8 Fe 0.2 O 3-δ as a result of the OER. Possible processes responsible for the structural change and enhanced OER activities are discussed.

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Metadata

Authors
Risch, M., Grimaud, A., May, K. J., Stoerzinger, K. A., Chen, T. J., Mansour, A. N., & Shao-Horn, Y.
Venue
The Journal of Physical Chemistry C
Published
2013-04-18
Volume
117
Issue
17
Pages
8628-8635
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2312362393
Cited by
353
References
27
FWCI
9.26
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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