The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Size-Dependent Photothermal Conversion Efficiencies of Plasmonically Heated Gold Nanoparticles
Abstract
We report the light-to-heat energy transfer efficiencies of gold nanoparticles with variable sizes by assessing the temperature profiles of laser-activated particle suspensions in water. Gold nanoparticles with sizes ranging from 5 to 50 nm were synthesized by chemical reduction methods using sodium borohydride, sodium citrate, or hydroquinone as reducing agents. As-synthesized gold nanoparticle solution (1 mL) was loaded into a quartz cuvette and exposed to a CW green laser (532 nm). Heat input into the system by energy transfer from nanoparticles equals heat dissipation at thermal equilibrium. The transducing efficiency was then determined by plotting temperature increase as a function of laser power extinction. The efficiency increases from 0.650 ± 0.012 to 0.803 ± 0.008 as the particle size decreases from 50.09 ± 2.34 to 4.98 ± 0.59 nm, respectively. The results indicate that the photothermal properties of gold nanoparticles are size-tunable, and the variation of efficiency can be correlated to the absorption/extinction ratios calculated by Mie theory for different particle sizes. We further expanded our Mie theory calculations of absorption/extinction ratios to a broader range of diameters and wavelengths. These studies are crucial for practical applications of gold nanoparticles in nanotechnology and bioengineering, such as enhancing the treatment efficiency of laser surgery.
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Cites
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Cited by
Surface plasmon resonance in gold nanoparticles: a review
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Gold-Nanoparticle-Assisted Plasmonic Photothermal Therapy Advances Toward Clinical Application
Ali, M. R. K., Wu, Y., & El-Sayed, M. A. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b01961 · Cited by 346
Plasmonic photothermal catalysis for solar-to-fuel conversion: current status and prospects
Luo, S., Ren, X., Lin, H., Song, H., & Ye, J. (2021) · Chemical Science · doi:10.1039/d1sc00064k · Cited by 298
Metadata
- Authors
- Jiang, K., Smith, D. A., & Pinchuk, A.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-17
- Volume
- 117
- Issue
- 51
- Pages
- 27073-27080
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2060676738
- Cited by
- 400
- References
- 32
- FWCI
- 4.24
- Type
- journal article
- Language
- en
- Open access
- closed
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