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Strong Thermal Transport Anisotropy and Strain Modulation in Single-Layer Phosphorene
Open accessAbstract
Using first-principles calculations and the nonequilibrium Green’s function method, we investigate ballistic thermal transport in two-dimensional monolayer phosphorene sheet. A significant crystallographic orientation dependence of thermal conductance is observed, with room temperature thermal conductance along zigzag direction being 40% higher than that along armchair direction. Furthermore, we find that the thermal conductance anisotropy with the orientation can be tuned by applying strain. In particular, the zigzag-oriented thermal conductance is enhanced when a zigzag-oriented strain is applied but decreases when an armchair-oriented strain is applied; whereas the armchair-oriented thermal conductance always decreases when either a zigzag- or an armchair-oriented strain is applied. The present work suggests that the remarkable thermal transport anisotropy and its strain-modulated effect in single-layer phosphorene may be used for thermal management in phosphorene-based electronics and optoelectronic devices.
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Cites
The electronic properties of graphene
Castro Neto, A. H., Guinea, F., Peres, N. M. R., Novoselov, K. S., & Geim, A. K. (2009) · Reviews of Modern Physics · doi:10.1103/revmodphys.81.109 · Cited by 24,803
Thermal properties of graphene and nanostructured carbon materials
Balandin, A. A. (2011) · Nature Materials · doi:10.1038/nmat3064 · Cited by 6,244
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Zhang, S., Guo, S., Chen, Z., Wang, Y., Gao, H., Gómez-Herrero, J., Ares, P., Zamora, F., Zhu, Z., & Zeng, H. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00125h · Cited by 850
Strongly anisotropic in-plane thermal transport in single-layer black phosphorene
Jain, A., & McGaughey, A. J. H. (2015) · Scientific Reports · doi:10.1038/srep08501 · Cited by 549
Rational Design of Flexible Two-Dimensional MXenes with Multiple Functionalities
Fu, Z., Wang, N., Legut, D., Si, C., Zhang, Q., Du, S., Germann, T. C., Francisco, J. S., & Zhang, R. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00348 · Cited by 396
Strain engineering in two-dimensional nanomaterials beyond graphene
Deng, S., Sumant, A. V., & Berry, V. (2018) · Nano Today · doi:10.1016/j.nantod.2018.07.001 · Cited by 369
Cai, Y., Zhang, G., & Zhang, Y.-W. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b02634 · Cited by 354
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Metadata
- Authors
- Ong, Z.-Y., Cai, Y., Zhang, G., & Zhang, Y.-W.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-22
- Volume
- 118
- Issue
- 43
- Pages
- 25272-25277
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2000361742
- Cited by
- 265
- References
- 2
- FWCI
- 16.23
- Type
- journal article
- Language
- en
- Open access
- green
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- Ong, Z.-Y., Cai, Y., Zhang, G., & Zhang, Y.-W. (2014). Strong Thermal Transport Anisotropy and Strain Modulation in Single-Layer Phosphorene. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp5079357
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