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Perovskite Oxide SrTiO3 as an Efficient Electron Transporter for Hybrid Perovskite Solar Cells

Bera, Ashok, Wu, Kewei, Sheikh, Arif, Alarousu, Erkki, Mohammed, Omar F., Wu, Tom·2014·The Journal of Physical Chemistry C

Abstract

In this work, we explored perovskite oxide SrTiO 3 (STO) for the first time as the electron-transporting layer in organolead trihalide perovskite solar cells. The steady-state photoluminescence (PL) quenching and transient absorption experiments revealed efficient photoelectron transfer from CH 3 NH 3 PbI 3– x Cl x to STO. Perovskite solar cells with meso -STO exhibit an open circuit voltage of 1.01 V, which is 25% higher than the value of 0.81 V achieved in the control device with the conventional meso -TiO 2 . In addition, an increase of 17% in the fill factor was achieved by tailoring the thickness of the meso -STO layer. We found that the application of STO leads to uniform perovskite layers with large grains and complete surface coverage, leading to a high shunt resistance and improved performance. These findings suggest STO as a competitive candidate as electron transport material in organometal perovskite solar cells.

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Metadata

Authors
Bera, A., Wu, K., Sheikh, A., Alarousu, E., Mohammed, O. F., & Wu, T.
Venue
The Journal of Physical Chemistry C
Published
2014-12-02
Volume
118
Issue
49
Pages
28494-28501
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2323440525
Cited by
303
References
3
FWCI
14.68
Type
journal article
Language
en
Open access
closed

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