The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Hydrogen Evolution on Supported Incomplete Cubane-type [Mo3S4]4+ Electrocatalysts
Abstract
Electrocatalytic properties of biomimetic supported incomplete cubane-type [Mo 3 S 4 ] 4+ clusters are investigated. The activity toward the hydrogen evolution reaction (HER) is evaluated on both a high surface area gas diffusion electrode in a membrane electrode assembly and on highly orientated pyrolytic graphite (HOPG) supports. Sub-monolayers of the clusters were imaged by means of scanning tunnelling microscopy (STM) prior to electrochemical characterization. This enabled the quantification of the activity on a per cluster basis for the HER and the comparison of the activity with other HER catalysts. We find that the HER activity of the [Mo 3 S 4 ] 4+ is comparable with that of the edge sites of MoS 2 . The supported [Mo 3 S 4 ] 4+ molecules were also characterized by X-ray photoelectron spectroscopy (XPS), and the observed deterioration in electrocatalytic activity with time was assigned to slow [Mo 3 S 4 ] 4+ cathodic desorption from the catalyst support.
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Citations
Cites
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Self-citationAlternative energy technologies
Dresselhaus, M. S., & Thomas, I. L. (2001) · Nature · doi:10.1038/35104599 · Cited by 4,894
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Self-citationBiomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Self-citationAbild-Pedersen, F., Greeley, J., Studt, F., Rossmeisl, J., Munter, T. R., Moses, P. G., Skúlason, E., Bligaard, T., & Nørskov, J. K. (2007) · Physical Review Letters · doi:10.1103/physrevlett.99.016105 · Cited by 1,678
Cited by
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Self-citationNoble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Self-citationEnhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution
Voiry, D., Yamaguchi, H., Li, J., Silva, R., Alves, D. C. B., Fujita, T., Chen, M., Asefa, T., Shenoy, V. B., Eda, G., et al. (2013) · Nature Materials · doi:10.1038/nmat3700 · Cited by 2,641
Metadata
- Authors
- Jaramillo, T. F., Bonde, J., Zhang, J., Ooi, B.-L., Andersson, K., Ulstrup, J., & Chorkendorff, I.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-10-17
- Volume
- 112
- Issue
- 45
- Pages
- 17492-17498
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2087072090
- Cited by
- 233
- References
- 5
- FWCI
- 1.89
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jaramillo, T. F., Bonde, J., Zhang, J., Ooi, B.-L., Andersson, K., Ulstrup, J., & Chorkendorff, I. (2008). Hydrogen Evolution on Supported Incomplete Cubane-type [Mo3S4]4+ Electrocatalysts. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp802695e
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