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Hydrogen Evolution on Supported Incomplete Cubane-type [Mo3S4]4+ Electrocatalysts
Abstract
Electrocatalytic properties of biomimetic supported incomplete cubane-type [Mo 3 S 4 ] 4+ clusters are investigated. The activity toward the hydrogen evolution reaction (HER) is evaluated on both a high surface area gas diffusion electrode in a membrane electrode assembly and on highly orientated pyrolytic graphite (HOPG) supports. Sub-monolayers of the clusters were imaged by means of scanning tunnelling microscopy (STM) prior to electrochemical characterization. This enabled the quantification of the activity on a per cluster basis for the HER and the comparison of the activity with other HER catalysts. We find that the HER activity of the [Mo 3 S 4 ] 4+ is comparable with that of the edge sites of MoS 2 . The supported [Mo 3 S 4 ] 4+ molecules were also characterized by X-ray photoelectron spectroscopy (XPS), and the observed deterioration in electrocatalytic activity with time was assigned to slow [Mo 3 S 4 ] 4+ cathodic desorption from the catalyst support.
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Metadata
- Authors
- Jaramillo, T. F., Bonde, J., Zhang, J., Ooi, B.-L., Andersson, K., Ulstrup, J., & Chorkendorff, I.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-10-17
- Volume
- 112
- Issue
- 45
- Pages
- 17492-17498
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2087072090
- Cited by
- 233
- References
- 5
- FWCI
- 1.89
- Type
- journal article
- Language
- en
- Open access
- closed
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