Anomalous Surfactant-Induced Enhancement of Luminescence Quantum Yield of Cyanine Dye J-Aggregates
Abstract
Formation of the “J-aggregate-surfactant” complex for three cyanine dyes (L-21, LC-1 and PIC) in binary solutions containing cationic surfactant CPB at the concentration higher than the critical micelle concentration has been observed. The complex formation causes a significant increase of J-aggregate luminescence quantum yield and a decrease of radiative lifetime. The model of exciton self-trapping suppression in the “J-aggregate-surfactant” complex that causes changes of luminescence parameters has been proposed.
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Currently reported J-aggregates formed in an aqueous environment, in particular polymethine-based J-aggregates, generally showed relatively low Φfl.
“It is important to stress that the currently reported J-aggregates formed in an aqueous environment, in particular, polymethine-based J-aggregates, generally showed relatively low Φfl.121−124”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [124]
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Self-citation
- Authors
- Guralchuk, G. Y., Katrunov, I. K., Grynyov, R. S., Sorokin, A. V., Yefimova, S. L., Borovoy, I. A., & Malyukin, Y. V.
- Affiliations
- Institute for Scintillation Materials (UA)
- Institute for Scintillation Materials, NAS of Ukraine, 60 Lenin ave., 61001 Kharkov, Ukraine
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-08-29
- Volume
- 112
- Issue
- 38
- Pages
- 14762-14768
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W1965416322
- Cited by
- 64
- References
- 48
- Citations by year
- 2026: 2 · 2024: 2 · 2023: 8 · 2022: 6 · 2021: 9 · 2020: 4 · 2018: 4 · 2017: 4 · 2016: 2 · 2015: 1 · 2014: 4 · 2013: 2 · 2012: 4
- FWCI
- 2.45
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Physical Chemistry C (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
- Physical Sciences › Chemistry › Organic Chemistry › Surfactants and Colloidal Systems
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Keywords
- cyanine dyes, J-aggregates, cationic surfactants, cetylpyridinium bromide, luminescence quantum yield, radiative lifetime, exciton self-trapping, critical micelle concentration, binary solutions
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