The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Influence of Different Substituents on the Surface Composition of Ionic Liquids Studied Using ARXPS
Abstract
Angle resolved X-ray photoelectron spectroscopy has been used to study the surface composition of various nonfunctionalized and functionalized 1,3-dialkylimidazolium ionic liquids. For [C n C 1 Im][Tf 2 N] (where n = 2−16), an enrichment of the aliphatic carbon was observed for longer chains ( n ≥ 4). Enrichment of the aliphatic carbon also occurs for alkyl chains attached to the anion, as observed for [C 2 C 1 Im][OcOSO 3 ]. Oligo(ethyleneglycol)ether (PEG) functionalities in the cation lead to a surface composition close to bulk stoichiometry and thus a loss in enrichment of the chains. This effect is attributed to attractive interactions between the oxygen atoms on the cation to the hydrogen atoms on the imidazolium ring for [Et(EG) 2 MIm][Tf 2 N] and [Me(EG) 3 MIm][Tf 2 N].
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Citations
Cites
Applications of ionic liquids in the chemical industry
Plechkova, N. V., & Seddon, K. R. (2008) · Chem. Soc. Rev. · doi:10.1039/b006677j · Cited by 5,686
H. Davis, J. (2004) · Chemistry Letters · doi:10.1246/cl.2004.1072 · Cited by 1,053
Kuhlmann, E., Himmler, S., Giebelhaus, H., & Wasserscheid, P. (2007) · Green Chem. · doi:10.1039/b611974c · Cited by 150
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New Frontiers in Materials Science Opened by Ionic Liquids
Torimoto, T., Tsuda, T., Okazaki, K., & Kuwabata, S. (2010) · Advanced Materials · doi:10.1002/adma.200902184 · Cited by 869
Cremer, T., Kolbeck, C., Lovelock, K. R. J., Paape, N., Wölfel, R., Schulz, P. S., Wasserscheid, P., Weber, H., Thar, J., Kirchner, B., et al. (2010) · Chemistry – A European Journal · doi:10.1002/chem.201001032 · Cited by 305
Self-citationDensity and Surface Tension of Ionic Liquids
Kolbeck, C., Lehmann, J., Lovelock, K. R. J., Cremer, T., Paape, N., Wasserscheid, P., Fröba, A. P., Maier, F., & Steinrück, H.-P. (2010) · The Journal of Physical Chemistry B · doi:10.1021/jp1068413 · Cited by 269
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Metadata
- Authors
- Lovelock, K. R. J., Kolbeck, C., Cremer, T., Paape, N., Schulz, P. S., Wasserscheid, P., Maier, F., & Steinrück, H.-P.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-02-10
- Volume
- 113
- Issue
- 9
- Pages
- 2854-2864
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W4249891609
- Cited by
- 197
- References
- 3
- FWCI
- 7.73
- Type
- journal article
- Language
- en
- Open access
- closed
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