Imidazolium dialkylphosphates—a class of versatile, halogen-free and hydrolytically stable ionic liquids
Abstract
In this article a systematic and detailed study on the synthesis and the properties of dialkylphosphate ionic liquids is presented. This class of halogen-free ionic liquids is easily available in high quality and great variability by direct alkylation of nucleophiles, such as 1-methylimidazole, 1-ethylimidazole, 1-butylimidazole and 1-(2-methoxyethyl)-imidazole with different trialkylphosphates, such as trimethylphosphate, triethylphosphate or tributylphosphate. In general, these dialkylphosphate ionic liquids were found to display very attractive physico-chemical properties with great technical potential, especially in low temperature (<200 °C) applications with water present. For this specific application area, the materials described here clearly show superior properties compared with alkylsulfate ionic liquids due to their obviously much higher hydrolytic stability.
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Only a few solvents are able to dissolve crystalline cellulose fibrils, e.g. NMO or concentrated phosphoric acid, none of which are applied in lignocellulose processing.
“Only a few solvents are able to dissolve the crystalline polymer fibrils, e.g.N-methylmorpholine-N-oxide (NMO) 63 or concentrated phosphoric acid, 64 none of which are applied in lignocellulose processing.”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [63]
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- Authors
- Kuhlmann, E., Himmler, S., Giebelhaus, H., & Wasserscheid, P.
- Affiliations
- Friedrich-Alexander-Universität Erlangen-Nürnberg (DE)
- Corresponding author
- Wasserscheid, Peter
- ORCID
- Wasserscheid, Peter
- Venue
- Green Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2007
- Volume
- 9
- Issue
- 3
- Pages
- 233-242
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2169583514
- Cited by
- 150
- References
- 18
- Citations by year
- 2026: 1 · 2025: 6 · 2024: 2 · 2023: 6 · 2022: 4 · 2021: 5 · 2020: 4 · 2019: 11 · 2018: 7 · 2017: 7 · 2016: 9 · 2015: 18 · 2014: 9 · 2013: 5 · 2012: 9
- FWCI
- 2.47
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Green Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Engineering › Mechanical Engineering › Lubricants and Their Additives
- Physical Sciences › Chemistry › Organic Chemistry › Surfactants and Colloidal Systems
- Keywords
- halogen-free ionic liquids, hydrolytic stability, ionic liquid synthesis, trialkyl phosphates, 1-methylimidazole, low-temperature applications
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