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Cited by 313

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Aggregation-Induced Emission in the Crystals of 9,10-Distyrylanthracene Derivatives: The Essential Role of Restricted Intramolecular Torsion

He, Jiating, Xu, Bin, Chen, Feipeng, Xia, Haijian, Li, Kunpeng, Ye, Ling, Tian, Wenjing·2009·The Journal of Physical Chemistry C

Abstract

We have studied the crystal structures and photophysical properties of four 9,10-distyrylanthracene (DSA) derivatives. Their crystal structures exhibit nonplanar conformations due to the supramolecular interactions resulting in rigid molecules and relative tight stacking. The four DSA derivatives possess a typical aggregation-induced emission (AIE) property, i.e., they exhibit faint emission in their solutions but intense emission in their crystals as a result of the dominant nonradiative decay by free intramolecular torsion in the solution and the restricted torsional motion by supramolecular interaction in the crystal. The investigation of the relationship between the crystal structures and AIE properties of the four DSA derivatives indicates that DSA moiety is the key factor of AIE property because of the restricted intramolecular torsion between the 9,10-anthrylene core and the vinylene moiety.

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Metadata

Authors
He, J., Xu, B., Chen, F., Xia, H., Li, K., Ye, L., & Tian, W.
Venue
The Journal of Physical Chemistry C
Published
2009-05-08
Volume
113
Issue
22
Pages
9892-9899
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2111876724
Cited by
313
References
26
FWCI
5.74
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Aggregation-Induced Emission in the Crystals of 9,10-Distyrylanthracene Derivatives: The Essential Role of Restricted Intramolecular Torsion. https://app.cochat.ai/papers/10.1021/jp900205k
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He, J., Xu, B., Chen, F., Xia, H., Li, K., Ye, L., & Tian, W. (2009). Aggregation-Induced Emission in the Crystals of 9,10-Distyrylanthracene Derivatives: The Essential Role of Restricted Intramolecular Torsion. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp900205k

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