The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Water Adsorption on α-Fe2O3(0001) at near Ambient Conditions
Abstract
We have investigated hydroxylation and water adsorption on α-Fe 2 O 3 (0001) at water vapor pressures up to 2 Torr and temperatures ranging from 277 to 647 K (relative humidity (RH) ≤ 34%) using ambient-pressure X-ray photoelectron spectroscopy (XPS). Hydroxylation occurs at the very low RH of 1 × 10 −7 % and precedes the adsorption of molecular water. With increasing RH, the OH coverage increases up to one monolayer (ML) without any distinct threshold pressure. Depth profiling measurements showed that hydroxylation occurs only at the topmost surface under our experimental conditions. The onset of molecular water adsorption varies from ∼2 × 10 −5 to ∼4 × 10 −2 % RH depending on sample temperature and water vapor pressure. The coverage of water reaches 1 ML at ∼15% RH and increases to 1.5 ML at 34% RH.
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Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Kocar, B. D., Polizzotto, M. L., Benner, S. G., Ying, S. C., Ung, M., Ouch, K., Samreth, S., Suy, B., Phan, K., Sampson, M., et al. (2008) · Applied Geochemistry · doi:10.1016/j.apgeochem.2008.06.026 · Cited by 161
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Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Parkinson, G. S. (2016) · Surface Science Reports · doi:10.1016/j.surfrep.2016.02.001 · Cited by 608
Liao, P., Keith, J. A., & Carter, E. A. (2012) · Journal of the American Chemical Society · doi:10.1021/ja301567f · Cited by 577
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies
Yang, Y., Peltier, C. R., Zeng, R., Schimmenti, R., Li, Q., Huang, X., Yan, Z., Potsi, G., Selhorst, R., Lu, X., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00331 · Cited by 544
Metadata
- Authors
- Yamamoto, S., Kendelewicz, T., Newberg, J. T., Ketteler, G., Starr, D. E., Mysak, E. R., Andersson, K. J., Ogasawara, H., Bluhm, H., Salmeron, M., Brown, G. E., & Nilsson, A.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-01-13
- Volume
- 114
- Issue
- 5
- Pages
- 2256-2266
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2076843280
- Cited by
- 291
- References
- 2
- FWCI
- 6.82
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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