Single-atom catalysis of CO oxidation using Pt1/FeOx
Abstract
Platinum-based heterogeneous catalysts are critical to many important commercial chemical processes, but their efficiency is extremely low on a per metal atom basis, because only the surface active-site atoms are used. Catalysts with single-atom dispersions are thus highly desirable to maximize atom efficiency, but making them is challenging. Here we report the synthesis of a single-atom catalyst that consists of only isolated single Pt atoms anchored to the surfaces of iron oxide nanocrystallites. This single-atom catalyst has extremely high atom efficiency and shows excellent stability and high activity for both CO oxidation and preferential oxidation of CO in H2. Density functional theory calculations show that the high catalytic activity correlates with the partially vacant 5d orbitals of the positively charged, high-valent Pt atoms, which help to reduce both the CO adsorption energy and the activation barriers for CO oxidation.
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Among PGM-free catalysts, composites involving single-atom moieties, i.e., transition metal-nitrogen-carbon (M-N-C) catalysts, are emerging.
“Among various PGM-free catalysts, composites involving so-called single-atom moieties are emerging [46], i.e., transition metal-nitrogen-carbon (M-N-C) catalysts.”
From Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly (2023) · cites this paper as [46]
Differences in the oxidation state of Cu is another potential factor that may alter CO2RR activity.
“Differences in the oxidation state of Cu is another potential factor that may alter CO2RR activity.[92,93]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [93]
Dinh et al. demonstrated that thermally deposited Cu nanoparticle can exhibit ~83% selectivity towards C2+ products, with ethylene (66%) the primary product at 275 mA/cm2 and -0.54 V vs RHE.
“In a recent study, Dinh et al. demonstrated that thermally deposited Cu nanoparticle can exhibit ~83% selectivity towards C2+ products, with ethylene (66%) the primary product at 275 mA/cm 2 and -0.54 V vs RHE.[93]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [93]
Liquid phase electrolyzers have achieved high current densities toward CO, formate, and multi-carbon hydrocarbons/oxygenates.
“Liquid phase electrolyzer has achieved high current densities toward CO, [128][129][130][131][132][133] formate, [134][135][136] and multi-carbon hydrocarbons/oxygenates. [93,111,114,137,138]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [93]
Physical vapor deposition methods used in the semiconductor industry, such as evaporation and sputtering, are amenable to large scale production and can controllably deposit sub-micron thicknesses of catalyst materials.
“Moreover, physical vapor deposition methods used in the semiconductor industry, such as evaporation and sputtering as used by Dinh et al. for CO2RR, [93] are amenable to large scale production and can controllably deposit sub-micron thicknesses of catalyst materials.”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [93]
Cites
Size- and support-dependency in the catalysis of gold
Haruta, M. (1997) · Catalysis Today · doi:10.1016/s0920-5861(96)00208-8 · Cited by 4,134 · see citing works
Haruta, M. (1989) · Journal of Catalysis · doi:10.1016/0021-9517(89)90034-1 · Cited by 3,190 · see citing works
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
Fu, Q. J., Saltsburg, H. M., & Flytzani‐Stephanopoulos, M. (2003) · Science · doi:10.1126/science.1085721 · Cited by 2,967 · see citing works
Low-temperature oxidation of CO catalysed by Co3O4 nanorods
Xie, X., Li, Y., Liu, Z., Haruta, M., & Shen, W. (2009) · Nature · doi:10.1038/nature07877 · Cited by 2,615 · see citing works
The Structure of Catalytically Active Gold on Titania
Chen, M., & Goodman, D. W. (2004) · Science · doi:10.1126/science.1102420 · Cited by 1,623 · see citing works
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
Herzing, A. A., Kiely, C. J., Carley, A. F., Landon, P., & Hutchings, G. J. (2008) · Science · doi:10.1126/science.1159639 · Cited by 1,530 · see citing works
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au <sub>8</sub> Clusters on MgO
Yoon, B., Häkkinen, H., Landman, U., Wörz, A. S., Antonietti, J.-M., Abbet, S., Judai, K., & Heiz, U. (2005) · Science · doi:10.1126/science.1104168 · Cited by 1,430 · cited 1× · see citing works
“Although mass-selected clusters (or even single atoms) soft-landed on oxide supports are used for fundamental studie”
BackgroundSelective oxidation with dioxygen by gold nanoparticle catalysts derived from 55-atom clusters
Turner, M., Golovko, V. B., Vaughan, O. P. H., Abdulkin, P., Berenguer‐Murcia, Á., Tikhov, M. S., Johnson, B. F. G., & Lambert, R. M. (2008) · Nature · doi:10.1038/nature07194 · Cited by 1,325 · see citing works
Catalysis of Gold Nanoparticles Deposited on Metal Oxides
Haruta, M. (2002) · CATTECH · doi:10.1023/a:1020181423055 · Cited by 1,120 · see citing works
Characterization of oxide surfaces and zeolites by carbon monoxide as an IR probe molecule
Hadjiivanov, K., & Vayssilov, G. N. (2002) · Advances in catalysis · doi:10.1016/s0360-0564(02)47008-3 · Cited by 1,094 · see citing works
Kwak, J. H., Hu, J. Z., Mei, D., Yi, C.-W., Kim, D. H., Peden, C. H. F., Allard, L. F., & Szanyi, J. (2009) · Science · doi:10.1126/science.1176745 · Cited by 1,043 · see citing works
Self-citationInterface-Confined Ferrous Centers for Catalytic Oxidation
Fu, Q., Li, W., Yao, Y., Liu, H., Su, H., Ma, D., Gu, X., Chen, L., Wang, Z., Zhang, H., et al. (2010) · Science · doi:10.1126/science.1188267 · Cited by 1,013 · see citing works
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
Yu, L., Mehmood, F., Lee, S., et al. (2010) · Science · doi:10.1126/science.1185200 · Cited by 883 · see citing works
Gas‐Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single‐Site Catalysts
Böhme, D. K., & Schwarz, H. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200461698 · Cited by 856 · see citing works
Vajda, Š., Pellin, M. J., Greeley, J., Marshall, C. L., Curtiss, L. A., Ballentine, G., Elam, J. W., Catillon-Mucherie, S., Redfern, P. C., Mehmood, F., et al. (2009) · Nature Materials · doi:10.1038/nmat2384 · Cited by 819 · see citing works
CO Oxidation on Pt(111): AnAb InitioDensity Functional Theory Study
Alavi, A., Hu, P., Deutsch, T., et al. (1998) · Physical Review Letters · doi:10.1103/physrevlett.80.3650 · Cited by 786 · see citing works
Electronic Structure Controls Reactivity of Size-Selected Pd Clusters Adsorbed on TiO 2 Surfaces
Kaden, W. E., Wu, T., Kunkel, W. A., et al. (2009) · Science · doi:10.1126/science.1180297 · Cited by 633 · see citing works
Z-contrast stem for materials science
Pennycook, S. J. (1989) · Ultramicroscopy · doi:10.1016/0304-3991(89)90173-3 · Cited by 583 · see citing works
Direct Sub-Angstrom Imaging of a Crystal Lattice
Nellist, P. D., Chisholm, M. F., Dellby, N., et al. (2004) · Science · doi:10.1126/science.1100965 · Cited by 533 · see citing works
The Hematite ( α- Fe2O3) (0001) Surface: Evidence for Domains of Distinct Chemistry
Wang, X.-G., Weiß, W., Shaikhutdinov, S. K., et al. (1998) · Physical Review Letters · doi:10.1103/physrevlett.81.1038 · Cited by 514 · see citing works
Enhanced Bonding of Gold Nanoparticles on Oxidized TiO 2 (110)
Matthey, D., Wang, J. G., Wendt, S., Matthiesen, J., Schaub, R., Lægsgaard, E., Hammer, B., & Besenbacher, F. (2007) · Science · doi:10.1126/science.1135752 · Cited by 481 · see citing works
Three-dimensional atomic-scale structure of size-selected gold nanoclusters
Li, Z. Y., Young, N. P., Vece, M. D., Palomba, S., Palmer, R. E., Bleloch, A. L., Curley, B. C., Johnston, R. L., Jiang, J., & Yuan, J. T. (2007) · Nature · doi:10.1038/nature06470 · Cited by 442 · see citing works
Pozdnyakova, O., Teschner, D., Wootsch, A., et al. (2005) · Journal of Catalysis · doi:10.1016/j.jcat.2005.10.014 · Cited by 423 · see citing works
CO Oxidation on Rutile‐Supported Au Nanoparticles
Remediakis, I. N., López, N., & Nørskov, J. K. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200461699 · Cited by 409 · see citing works
CO Oxidation on Aun/TiO2 Catalysts Produced by Size-Selected Cluster Deposition
Lee, S., Fan, C., Wu, T., & Anderson, S. L. (2004) · Journal of the American Chemical Society · doi:10.1021/ja049436v · Cited by 348 · see citing works
Direct Imaging of the Atomic Configuration of Ultradispersed Catalysts
Nellist, P. D., & Pennycook, S. J. (1996) · Science · doi:10.1126/science.274.5286.413 · Cited by 324 · see citing works
Bazin, P., Saur, O., Lavalley, J. C., et al. (2004) · Physical Chemistry Chemical Physics · doi:10.1039/b414159h · Cited by 293 · see citing works
Water Adsorption on α-Fe2O3(0001) at near Ambient Conditions
Yamamoto, S., Kendelewicz, T., Newberg, J. T., Ketteler, G., Starr, D. E., Mysak, E. R., Andersson, K. J., Ogasawara, H., Bluhm, H., Salmerón, M., et al. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp909876t · Cited by 292 · see citing works
Structures of Platinum Clusters: Planar or Spherical?
Xiao, L., & Wang, L. (2004) · The Journal of Physical Chemistry A · doi:10.1021/jp0485035 · Cited by 280 · see citing works
Dopants adsorbed as single atoms prevent degradation of catalysts
Wang, S., Borisevich, A. Y., Rashkeev, S. N., et al. (2004) · Nature Materials · doi:10.1038/nmat1077 · Cited by 231 · see citing works
Correlation between CO frequency and Pt coordination number. A DRIFT study on supported Pt catalysts
Kappers, M. J., & van der Maas, J. H. (1991) · Catalysis Letters · doi:10.1007/bf00769171 · Cited by 217 · see citing works
Direct imaging of single metal atoms and clusters in the pores of dealuminated HY zeolite
Ortalan, V., Uzun, A., Gates, B. C., & Browning, N. D. (2010) · Nature Nanotechnology · doi:10.1038/nnano.2010.92 · Cited by 193 · see citing works
Low-Temperature Cluster Catalysis
Judai, K., Abbet, S., Wörz, A. S., et al. (2004) · Journal of the American Chemical Society · doi:10.1021/ja039037k · Cited by 168 · see citing works
The interpretation of CO adsorbed on Pt/SiO2 of two different particle-size distributions
Brandt, R. K., Hughes, M., Bourget, L., et al. (1993) · Surface Science · doi:10.1016/0039-6028(93)90552-u · Cited by 133 · see citing works
Stepped single-crystal surfaces as models for small catalyst particles
Greenler, R. G., Burch, K. D., Kretzschmar, K., et al. (1985) · Surface Science · doi:10.1016/0039-6028(85)90163-3 · Cited by 130 · see citing works
Thevuthasan, S., Kim, Y. J., Yi, S. I., et al. (1999) · Surface Science · doi:10.1016/s0039-6028(99)00200-9 · Cited by 123 · see citing works
Uzun, A., Ortalan, V., Browning, N. D., et al. (2009) · Journal of Catalysis · doi:10.1016/j.jcat.2009.11.017 · Cited by 118 · see citing works
QIAO, B., Liu, L., Zhang, J., et al. (2008) · Journal of Catalysis · doi:10.1016/j.jcat.2008.11.012 · Cited by 115 · see citing works
Self-citationWasserman, E. A., Rustad, J. R., Felmy, A. R., et al. (1997) · Surface Science · doi:10.1016/s0039-6028(97)00144-1 · Cited by 111 · see citing works
Pennycook, S. J., Chisholm, M. F., Lupini, A. R., et al. (2009) · Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences · doi:10.1098/rsta.2009.0112 · Cited by 99 · see citing works
The adsorption of CO on group 10 (Ni, Pd, Pt) transition-metal clusters
Gruene, P., Fielicke, A., Meijer, G., et al. (2008) · Physical Chemistry Chemical Physics · doi:10.1039/b808341j · Cited by 96 · see citing works
Uzun, A., Ortalan, V., Hao, Y., et al. (2009) · ACS Nano · doi:10.1021/nn9008142 · Cited by 85 · see citing works
A LEED analysis of the clean surfaces of α-Fe2O3(0001) and α-Cr2O3(0001) bulk single crystals
Lübbe, M., & Moritz, W. (2009) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/21/13/134010 · Cited by 76 · see citing works
Origin of Anomalous Pt–Pt Distances in the Pt/Alumina Catalytic System
Sohlberg, K. W., Rashkeev, S. N., Borisevich, A. Y., et al. (2004) · ChemPhysChem · doi:10.1002/cphc.200400212 · Cited by 73 · see citing works
Allard, L. F., Borisevich, A. Y., Deng, W., et al. (2009) · Journal of Electron Microscopy · doi:10.1093/jmicro/dfp016 · Cited by 72 · see citing works
Self-citationStructurally simple supported platinum clusters prepared from [Pt15(CO)30]2- on magnesium oxide
Chang, J.-R., Koningsberger, D. C., & Gates, B. C. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00042a025 · Cited by 70 · see citing works
Preferential oxidation of CO under excess H2H2 conditions over iridium catalysts
HUANG, Y., Wang, A., Wang, X., & Zhang, T. (2007) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2007.03.031 · Cited by 65 · see citing works
Self-citationQiao, B., & Deng, Y. (2003) · Chemical Communications · doi:10.1039/b307181b · Cited by 55 · see citing works
Self-citationXANES study of the support effect on the state of platinum catalysts
Yoshida, H., Yazawa, Y., Takagi, N., et al. (1999) · Journal of Synchrotron Radiation · doi:10.1107/s0909049598017919 · Cited by 53 · see citing works
Adsorption of V on a hematite (0001) surface and its oxidation: Submonolayer coverage
Jin, J., Ma, X., Kim, C., et al. (2007) · Surface Science · doi:10.1016/j.susc.2007.05.028 · Cited by 29 · see citing works
Flagged first, then by citations
Cited by
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Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239 · see citing works
Self-citationPlatinum single-atom and cluster catalysis of the hydrogen evolution reaction
Cheng, N., Stambula, S., Wang, D., Banis, M. N., Liu, J., Riese, A., Xiao, B., Li, R., Sham, T.-K., Liu, L.-M., et al. (2016) · Nature Communications · doi:10.1038/ncomms13638 · Cited by 2,072 · see citing works
Self-citationWu, W., Wu, Z., Yu, T., Jiang, C., & Kim, W.-S. (2015) · Science and Technology of Advanced Materials · doi:10.1088/1468-6996/16/2/023501 · Cited by 1,574 · see citing works
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331 · see citing works
Catalysis by Supported Single Metal Atoms
Liu, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b01534 · Cited by 1,331 · see citing works
Self-citationAnchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution
Xue, Y., Huang, B., Yi, Y., Guo, Y., Zuo, Z., Li, Y., Jia, Z., Liu, H., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03896-4 · Cited by 1,011 · see citing works
Yang, S., Kim, J., Tak, Y. J., Soon, A., & Lee, H. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201509241 · Cited by 899 · see citing works
Cao, L., Luo, Q., Liu, W., Lin, Y., Liu, X., Cao, Y., Zhang, W., Wu, Y., Yang, J., Yao, T., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0203-5 · Cited by 901 · see citing works
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887 · see citing works
Self-citationTuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst
Choi, C. H., Kim, M., Kwon, H. C., Cho, S. J., Yun, S., Kim, H.-T., Mayrhofer, K. J. J., Kim, H., & Choi, M. (2016) · Nature Communications · doi:10.1038/ncomms10922 · Cited by 849 · see citing works
Zhou, K. L., Wang, Z., Han, C. B., Ke, X., Wang, C., Jin, Y., Zhang, Q., Liu, J., Wang, H., & Yan, H. (2021) · Nature Communications · doi:10.1038/s41467-021-24079-8 · Cited by 765 · see citing works
Self-citationFang, S., Zhu, X., Liu, X., Gu, J., Liu, W., Wang, D., Zhang, W., Lin, Y., Lu, J., Wei, S., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-14848-2 · Cited by 585 · see citing works
Back, S., Lim, J., Kim, N.-Y., Kim, Y.-H., & Jung, Y. (2017) · Chemical Science · doi:10.1039/c6sc03911a · Cited by 542 · see citing works
Zhang, L., Han, L., Liu, H., Liu, X., & Luo, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201706921 · Cited by 532 · see citing works
2D graphdiyne: An emerging carbon material
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Phase-dependent growth of Pt on MoS2 for highly efficient H2 evolution
Shi, Z., Zhang, X., Lin, X., Liu, G., Ling, C., Xi, S., Chen, B., Ge, Y., Tan, C., Lai, Z., et al. (2023) · Nature · doi:10.1038/s41586-023-06339-3 · Cited by 463 · see citing works
Self-citationKong, T., Jiang, Y., & Xiong, Y. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00920e · Cited by 463 · see citing works
Zhu, Y., Wang, J., Koketsu, T., Kroschel, M., Chen, J.-M., Hsu, S.-Y., Henkelman, G., Hu, Z., Strasser, P., & Ma, J. (2022) · Nature Communications · doi:10.1038/s41467-022-35426-8 · Cited by 420 · see citing works
Jiang, K., Siahrostami, S., Akey, A. J., Li, Y., Lu, Z., Lattimer, J., Hu, Y., Stokes, C., Gangishetty, M., Chen, G., et al. (2017) · Chem · doi:10.1016/j.chempr.2017.09.014 · Cited by 406 · see citing works
Self-citationThe Power of Single‐Atom Catalysis
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Engineering Ruthenium-Based Electrocatalysts for Effective Hydrogen Evolution Reaction
Yang, Y., Yu, Y., Li, J., Chen, Q., Du, Y., Rao, P., Li, R., Jia, C., Kang, Z., Deng, P., et al. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00679-3 · Cited by 313 · see citing works
Self-citationSun, Q., Wang, N., Bing, Q., Si, R., Liu, J., Bai, R., Zhang, P., Jia, M., & Yu, J. (2017) · Chem · doi:10.1016/j.chempr.2017.07.001 · Cited by 303 · see citing works
Self-citationRecent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly
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“Among various PGM-free catalysts, composites involving so-called single-atom moieties are emerging [46], i.e., transition metal–nitrogen–carbon (M–”
Li, Y., Su, H., Chan, S. H., & Sun, Q. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01165 · Cited by 265 · see citing works
Lin, X., Hu, W., Xu, J., Liu, X., Jiang, W., Ma, X., He, D., Wang, Z., Li, W., Yang, L.-M., et al. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.3c13676 · Cited by 241 · see citing works
Wang, C., Guo, W., Chen, T., Lu, W., Song, Z., Yan, C., Feng, Y., Gao, F., Zhang, X., Rao, Y., et al. (2024) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2024.215899 · Cited by 184 · see citing works
Liu, H., Hu, Z., Liu, Q., Sun, P., Wang, Y., Chou, S., Hu, Z., & Zhang, Z. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta09538a · Cited by 176 · see citing works
Zhang, L., Jang, H., Wang, Y., Li, Z., Zhang, W., Kim, M. G., Yang, D., Liu, S., Liu, X., & Cho, J. (2021) · Advanced Science · doi:10.1002/advs.202004516 · Cited by 118 · see citing works
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He, Z., Du, J., Miao, Y., & Li, Y. (2023) · Advanced Healthcare Materials · doi:10.1002/adhm.202300234 · Cited by 105 · see citing works
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Li, J., Zhou, Y., Tang, W., Zheng, J., Gao, X., Wang, N., Chen, X., Wei, M., Xiao, X., & Chu, W. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119861 · Cited by 65 · see citing works
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Kim, M., Kim, S., Park, J., Lee, S., Jang, I., Kim, S., Lee, C. Y., Kwon, O. J., Ham, H. C., Hupp, J. T., et al. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202300673 · Cited by 34 · see citing works
- Authors
- Qiao, B., Wang, A., Yang, X., Allard, L. F., Jiang, Z., Cui, Y., Liu, J., Li, J., & Zhang, T.
- Affiliations
- Dalian Institute of Chemical Physics (CN)
- Tsinghua University (CN)
- Oak Ridge National Laboratory (US)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Liu, Jingyue
- Li, Jun
- Zhang, Tao
- ORCID
- Venue
- Nature Chemistry
- Published
- 2011-07-22
- Volume
- 3
- Issue
- 8
- Pages
- 634-641
- ISSN
- 1755-4330 (ISSN-L)
- 1755-4349
- OpenAlex
- W2134716155
- Cited by
- 7,526
- References
- 50
- Citations by year
- 2026: 763 · 2025: 895 · 2024: 878 · 2023: 896 · 2022: 906 · 2021: 799 · 2020: 688 · 2019: 536 · 2018: 412 · 2017: 257 · 2016: 169 · 2015: 117 · 2014: 99 · 2013: 70 · 2012: 37
- FWCI
- 32.46
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Nature Chemistry (publishedVersion)
- PubMed (publishedVersion)
- Dalian Institute of Chemical Physics, CAS Institutional Repository (submittedVersion)
- Funders
- Ministry of Science and Technology of the People's Republic of China
- Office of Energy Efficiency and Renewable Energy
- Oak Ridge National Laboratory
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Oxidation Reactions
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- single-atom catalysts, platinum single atoms, CO oxidation, atom economy, CO adsorption energy, catalyst stability, platinum reduction
- MeSH terms
- Adsorption, Carbon Monoxide, Catalysis, Ferric Compounds, Oxidation-Reduction, Platinum, Microscopy, Electron, Scanning Transmission, Spectroscopy, Fourier Transform Infrared
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