The DOI matches its Crossref record.
Formic Acid Oxidation on Ultrathin Pd Films on Au(hkl) and Pt(hkl) Electrodes
Abstract
The oxidation of formic acid on thin, epitaxially-grown Pd overlayers on Au and Pt single crystal electrodes was studied as a function of overlayer thickness ranging from submonolayer coverages up to the equivalent of 10 monolayers. The results were compared with those for massive Pd single crystal surfaces. The electrocatalytic properties of the Pd overlayers were found to depend markedly on their thickness and on their crystallographic orientation. Pd(100) showed the highest catalytic activity of all three low-index faces, and Pd films on Pt( hkl ), even when two or three layers thick, generally exhibited a much higher activity than Pd films on Au( hkl ) or massive Pd( hkl ). In all cases a high resistivity of the Pd surfaces against poisoning by CO was observed, which makes Pd an interesting alternative to the often quickly deactivated Pt as catalyst for organic fuel cell reactions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Shaping binary metal nanocrystals through epitaxial seeded growth
Habas, S. E., Lee, H., Radmilovic, V., Somorjai, G. A., & Yang, P. (2007) · Nature Materials · doi:10.1038/nmat1957 · Cited by 1,205
Zhang, J., Vukmirovic, M. B., Xu, Y., Mavrikakis, M., & Adzic, R. R. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462335 · Cited by 1,106
Tuning Reaction Rates by Lateral Strain in a Palladium Monolayer
Kibler, L. A., El‐Aziz, A. M., Hoyer, R., & Kolb, D. M. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462127 · Cited by 573
Self-citationJin, M., Zhang, H., Xie, Z., & Xia, Y. (2012) · Energy Environ. Sci. · doi:10.1039/c2ee02866b · Cited by 398
Shape control of platinum and palladium nanoparticles for catalysis
Cheong, S., Watt, J. D., & Tilley, R. D. (2010) · Nanoscale · doi:10.1039/c0nr00276c · Cited by 342
Hoshi, N., Kida, K., Nakamura, M., Nakada, M., & Osada, K. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0608372 · Cited by 277
Design of Noble Metal Electrocatalysts on an Atomic Level
Chao, T., Hu, Y., Hong, X., & Li, Y. (2019) · ChemElectroChem · doi:10.1002/celc.201801189 · Cited by 62
Metadata
- Authors
- Baldauf, M., & Kolb, D. M.
- Venue
- The Journal of Physical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 100
- Issue
- 27
- Pages
- 11375-11381
- ISSN
- 0022-3654 (ISSN-L)
- 1541-5740
- OpenAlex
- W2031212116
- Cited by
- 389
- References
- 0
- FWCI
- 4.26
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
