The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Photooxidation of Organic Chemicals Catalyzed by Nanoscale MoS2
Abstract
We describe experiments that explore the use of nanosize MoS 2 semiconductors for catalyzing the photooxidation of an organic chemical, phenol. The band gap of nanoscale MoS 2 can be tuned across the visible spectrum and we show that d = 4.5 nm MoS 2 which has an absorbance edge near 550 nm photooxidizes phenol using only visible light (>450 nm) while smaller band gap d = 8−10 nm MoS 2 or wide band gap Degussa P-25 TiO 2 do not. The possibility of increasing the rate of photooxidation of phenol by deposition of nanoclusters of MoS 2 on bulk semiconductor powders is investigated. It is shown that small amounts (<5 wt %) of nanoscale MoS 2 deposited onto TiO 2 can lead to significant (∼2-fold) enhancements of phenol destruction rates compared to TiO 2 by itself.
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Cites
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Cited by
Xiang, Q., Yu, J., & Jaroniec, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302846n · Cited by 2,360
Sensing Behavior of Atomically Thin-Layered MoS2 Transistors
Late, D. J., Huang, Y.-K., Liu, B., Acharya, J., Shirodkar, S. N., Luo, J., Yan, A., Charles, D., Waghmare, U. V., Dravid, V. P., et al. (2013) · ACS Nano · doi:10.1021/nn400026u · Cited by 1,374
Environmental Applications of 2D Molybdenum Disulfide (MoS2) Nanosheets
Wang, Z., & Mi, B. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.7b01466 · Cited by 914
Meng, F., Li, J., Cushing, S. K., Zhi, M., & Wu, N. (2013) · Journal of the American Chemical Society · doi:10.1021/ja404851s · Cited by 643
Catalytic Properties of Single Layers of Transition Metal Sulfide Catalytic Materials
Chianelli, R. R., Siadati, M. H., De la Rosa, M. P., Berhault, G., Wilcoxon, J. P., Bearden, R., & Abrams, B. L. (2006) · Catalysis Reviews · doi:10.1080/01614940500439776 · Cited by 304
Self-citation
Metadata
- Authors
- Thurston, T. R., & Wilcoxon, J. P.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-12-16
- Volume
- 103
- Issue
- 1
- Pages
- 11-17
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2048654006
- Cited by
- 250
- References
- 1
- FWCI
- 7.97
- Type
- journal article
- Language
- en
- Open access
- closed
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