The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Pyrrolidinium Imides: A New Family of Molten Salts and Conductive Plastic Crystal Phases
Abstract
A new family of molten salts is reported, based on the N -alkyl, N -alkyl pyrrolidinium cation and the bis(trifluoromethane sulfonyl)imide anion. Some of the members of the family are molten at room temperature, while the smaller and more symmetrical members have melting points around 100 °C. Of the room-temperature molten salt examples, the methyl butyl derivative exhibits the highest conductivity; at 2 × 10 -3 S/cm this is the highest molten salt conductivity observed to date at room temperature among the ammonium salts. This highly conductive behavior is rationalized in terms of the role of cation planarity. The salts also exhibit multiple crystalline phase behavior below their melting points and exhibit significant conductivity in at least their higher temperature crystal phase. For example, the methyl propyl derivative (mp = 12 °C) shows ion conductivity of 1 × 10 -6 S/cm at 0 °C in its higher temperature crystalline phase.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts
Bonhôte, P., Dias, A.-P., Papageorgiou, N., Kalyanasundaram, K., & Grätzel, M. (1996) · Inorganic Chemistry · doi:10.1021/ic951325x · Cited by 4,358
Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids
Wilkes, J. S., & Zaworotko, M. J. (1992) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39920000965 · Cited by 1,883
Wilkes, J. S., Levisky, J. A., Wilson, R. A., & Hussey, C. L. (1982) · Inorganic Chemistry · doi:10.1021/ic00133a078 · Cited by 1,458
Plastic crystals: A historical review
Timmermans, J. (1961) · Journal of Physics and Chemistry of Solids · doi:10.1016/0022-3697(61)90076-2 · Cited by 850
Room-Temperature Molten Salts Based on the Quaternary Ammonium Ion
Sun, J., Forsyth, M., & MacFarlane, D. R. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp981159p · Cited by 486
Self-citationFuller, J., Carlin, R. T., De Long, H. C., & Haworth, D. (1994) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39940000299 · Cited by 367
Ambient temperature plastic crystal fast ion conductors (PLICFICS)
COOPER, E., & Angell, C. A. (1986) · Solid State Ionics · doi:10.1016/0167-2738(86)90180-3 · Cited by 104
Thermodynamic aspects of the glass transition in liquids and plastic crystals
Angell, C. A. (1991) · Pure and Applied Chemistry · doi:10.1351/pac199163101387 · Cited by 80
Cited by
Deep Eutectic Solvents (DESs) and Their Applications
Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
How Ionic Are Room-Temperature Ionic Liquids? An Indicator of the Physicochemical Properties
Tokuda, H., Tsuzuki, S., Susan, M. A. B. H., Hayamizu, K., & Watanabe, M. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp064159v · Cited by 1,206
Energy storage in electrochemical capacitors: designing functional materials to improve performance
Hall, P. J., Mirzaeian, M., Fletcher, S. I., Sillars, F. B., Rennie, A. J. R., Shitta-Bey, G. O., Wilson, G., Cruden, A., & Carter, R. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00004c · Cited by 1,162
Ionic Liquids in Electrochemical Devices and Processes: Managing Interfacial Electrochemistry
MacFarlane, D. R., Forsyth, M., Howlett, P. C., Pringle, J. M., Sun, J., Annat, G., Neil, W., & Izgorodina, E. I. (2007) · Accounts of Chemical Research · doi:10.1021/ar7000952 · Cited by 710
Self-citation
Metadata
- Authors
- MacFarlane, D. R., Meakin, P., Sun, J., Amini, N., & Forsyth, M.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-03-26
- Volume
- 103
- Issue
- 20
- Pages
- 4164-4170
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2021219814
- Cited by
- 1,084
- References
- 8
- FWCI
- 9.64
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
