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High-Energy Cathode Materials (Li2MnO3–LiMO2) for Lithium-Ion Batteries
Abstract
Lithium-rich layered oxide materials xLi2MnO3·(1-x)LiMO2 (M = Mn, Ni, Co, Fe, Cr, etc.) have attracted much attention for the use of cathode materials in lithium-ion batteries in recent years. However, there are many issues still unclear (the structure and reaction mechanism are ambiguous until now), and numerous scientific challenges (low initial Coulombic efficiency, poor rate capability, and voltage degradation during cycling) of these materials that must be overcome to realize their utilization in commercial lithium-ion batteries. This Perspective focuses on the challenges and prospects associated with the current researching results of these lithium-rich layered cathode materials. Specifically, their average/local structures, reaction mechanisms, and electrochemical properties are discussed.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Thackeray, M. M., Wolverton, C., & Isaacs, E. D. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21892e · Cited by 2,515
Cited by
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Nayak, P. K., Yang, L., Brehm, W., & Adelhelm, P. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201703772 · Cited by 2,674
The development and future of lithium ion batteries
Blomgren, G. E. (2017) · Journal of The Electrochemical Society · doi:10.1149/2.0251701jes · Cited by 1,940
Nickel‐Rich and Lithium‐Rich Layered Oxide Cathodes: Progress and Perspectives
Manthiram, A., Knight, J. C., Myung, S., Oh, S., & Sun, Y. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201501010 · Cited by 1,202
Zhou, L., Zhang, K., Hu, Z., Tao, Z., Mai, L., Kang, Y., Chou, S., & Chen, J. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201701415 · Cited by 593
Oxygen Release Degradation in Li‐Ion Battery Cathode Materials: Mechanisms and Mitigating Approaches
Sharifi‐Asl, S., Lu, J., Amine, K., & Shahbazian‐Yassar, R. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201900551 · Cited by 532
Metadata
- Authors
- Yu, H., & Zhou, H.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-04-01
- Volume
- 4
- Issue
- 8
- Pages
- 1268-1280
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W309195963
- Cited by
- 624
- References
- 2
- FWCI
- 43.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yu, H., & Zhou, H. (2013). High-Energy Cathode Materials (Li2MnO3–LiMO2) for Lithium-Ion Batteries. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/jz400032v
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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