The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Photoinduced Giant Dielectric Constant in Lead Halide Perovskite Solar Cells
Abstract
Organic-inorganic lead trihalide perovskites have emerged as an outstanding photovoltaic material that demonstrated a high 17.9% conversion efficiency of sunlight to electricity in a short time. We have found a giant dielectric constant (GDC) phenomenon in these materials consisting on a low frequency dielectric constant in the dark of the order of ε0 = 1000. We also found an unprecedented behavior in which ε0 further increases under illumination or by charge injection at applied bias. We observe that ε0 increases nearly linearly with the illumination intensity up to an additional factor 1000 under 1 sun. Measurement of a variety of samples of different morphologies, compositions, and different types of contacts shows that the GDC is an intrinsic property of MAPbX3 (MA = CH3NH3(+)). We hypothesize that the large dielectric response is induced by structural fluctuations. Photoinduced carriers modify the local unit cell equilibrium and change the polarizability, assisted by the freedom of rotation of MA. The study opens a way for the understanding of a key aspect of the photovoltaic operation of high efficiency perovskite solar cells.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Kim, H.-S., Lee, C.-R., Im, J.-H., Lee, K.-B., Moehl, T., Marchioro, A., Moon, S.-J., Humphry-Baker, R., Yum, J.-H., Moser, J. E., et al. (2012) · Scientific Reports · doi:10.1038/srep00591 · Cited by 8,092
Cited by
Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation
Azpiroz, J. M., Mosconi, E., Bisquert, J., & De Angelis, F. (2015) · Energy & Environmental Science · doi:10.1039/c5ee01265a · Cited by 1,644
Self-citationBrenner, T. M., Egger, D. A., Kronik, L., Hodes, G., & Cahen, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2015.7 · Cited by 1,557
Tress, W., Marinova, N., Moehl, T., Zakeeruddin, S. M., Nazeeruddin, M. K., & Grätzel, M. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03664f · Cited by 1,381
Ahmadi, M., Wu, T., & Hu, B. (2017) · Advanced Materials · doi:10.1002/adma.201605242 · Cited by 820
Charge-Carrier Dynamics in Organic-Inorganic Metal Halide Perovskites
Herz, L. M. (2016) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-040215-112222 · Cited by 819
Metadata
- Authors
- Juarez-Perez, E. J., Sanchez, R. S., Badia, L., Garcia-Belmonte, G., Kang, Y. S., Mora-Sero, I., & Bisquert, J.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-06-24
- Volume
- 5
- Issue
- 13
- Pages
- 2390-2394
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2322944840
- Cited by
- 744
- References
- 1
- FWCI
- 50.59
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Photoinduced Giant Dielectric Constant in Lead Halide Perovskite Solar Cells. https://app.cochat.ai/papers/10.1021/jz5011169
- The paper
- Juarez-Perez, E. J., Sanchez, R. S., Badia, L., Garcia-Belmonte, G., Kang, Y. S., Mora-Sero, I., & Bisquert, J. (2014). Photoinduced Giant Dielectric Constant in Lead Halide Perovskite Solar Cells. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/jz5011169
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
