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Stable Dispersions of Fullerenes, C60 and C70, in Water. Preparation and Characterization

Deguchi, Shigeru, Alargova, Rossitza G., Tsujii, Kaoru·2001·Langmuir

Abstract

Stable aqueous dispersions of fullerenes, C 60 and C 70, were prepared by simply injecting into water a saturated solution of fullerene in tetrahydofuran (THF), followed by THF removal by purging gaseous nitrogen. To our knowledge, this is the first report of the stable dispersion of C 70 in water. Fullerenes are dispersed as monodisperse clusters in water, 60 nm in diameter. High resolution transmission electron microscopy revealed the polycrystalline nature of the cluster. The preparation of the dispersion is very easy to perform, and the dispersions thus obtained are of excellent colloidal stability even though no stabilizing agent is used. It was found that the surface of the cluster is negatively charged and the electrostatic repulsion between the negatively charged cluster surfaces is important for the stability of the dispersions.

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Metadata

Authors
Deguchi, S., Alargova, R. G., & Tsujii, K.
Venue
Langmuir
Published
2001-08-15
Volume
17
Issue
19
Pages
6013-6017
ISSN
  • 0743-7463 (ISSN-L)
  • 1520-5827
OpenAlex
W1975444379
Cited by
506
References
0
FWCI
4.81
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Stable Dispersions of Fullerenes, C60 and C70, in Water. Preparation and Characterization. https://app.cochat.ai/papers/10.1021/la010651o
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Deguchi, S., Alargova, R. G., & Tsujii, K. (2001). Stable Dispersions of Fullerenes, C60 and C70, in Water. Preparation and Characterization. Langmuir. https://doi.org/10.1021/la010651o

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