The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Solid Wettability from Surface Energy Components: Relevance to Pickering Emulsions
Abstract
A theoretical treatment is developed for the wetting of a solid particle at an oil−water interface in terms of the components of the surface energies of all three phases. Calculated oil−water contact angles for a solid of given hydrophobicity with a range of oils of different polarity show good agreement with experimental data. For a hydrophobically modified silica surface, oils of increasing polarity give higher oil−water contact angles measured through water. The results are in line with the effect of oil type on Pickering emulsion type where more polar oils preferentially give water-in-oil emulsions. The approach is also used to predict the type of solid particles that would be required to stabilize emulsions of two immiscible oils. For hydrocarbon−fluorocarbon pairs, it is predicted that perfluorinated particles would stabilize fluorocarbon-external emulsions while silica particles with a high coverage of hydrocarbon groups should stabilize hydrocarbon-external emulsions.
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Cites
Estimation of the surface free energy of polymers
Owens, D. K., & Wendt, R. C. (1969) · Journal of Applied Polymer Science · doi:10.1002/app.1969.070130815 · Cited by 9,476
Influence of Particle Wettability on the Type and Stability of Surfactant-Free Emulsions
Binks, B. P., & Lumsdon, S. O. (2000) · Langmuir · doi:10.1021/la000189s · Cited by 1,446
Self-citationAdditive and nonadditive surface tension components and the interpretation of contact angles
Van Oss, C. J., Good, R. J., & Chaudhury, M. K. (1988) · Langmuir · doi:10.1021/la00082a018 · Cited by 1,415
The Surface Tension of Pure Liquid Compounds
Jasper, J. J. (1972) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.3253106 · Cited by 1,233
The surface tension of pure liquid compounds
Zettlemoyer, A. C. (1974) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(74)90042-3 · Cited by 931
Pickering Emulsions Stabilized by Monodisperse Latex Particles: Effects of Particle Size
Binks, B. P., & Lumsdon, S. O. (2001) · Langmuir · doi:10.1021/la0103822 · Cited by 814
Self-citationFowkes, F. M. (1963) · The Journal of Physical Chemistry · doi:10.1021/j100806a008 · Cited by 747
Catastrophic Phase Inversion of Water-in-Oil Emulsions Stabilized by Hydrophobic Silica
Binks, B. P., & Lumsdon, S. O. (2000) · Langmuir · doi:10.1021/la991081j · Cited by 690
Self-citationPickering emulsions stabilised by Laponite clay particles
Ashby, N. P., & Binks, B. P. (2000) · Physical Chemistry Chemical Physics · doi:10.1039/b007098j · Cited by 504
Self-citationAdhesion under water: surface energy considerations
Clint, J. H., & Wicks, A. C. (2001) · International Journal of Adhesion and Adhesives · doi:10.1016/s0143-7496(00)00029-4 · Cited by 137
Self-citation
Cited by
Poly (lactic acid) blends: Processing, properties and applications
Nofar, M., Sacligil, D., Carreau, P. J., Kamal, M. R., & Heuzey, M.-C. (2019) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2018.12.002 · Cited by 780
Capillary forces generated by biomolecular condensates
Gouveia, B., Kim, Y., Shaevitz, J. W., Petry, S., Stone, H. A., & Brangwynne, C. P. (2022) · Nature · doi:10.1038/s41586-022-05138-6 · Cited by 270
Metadata
- Authors
- Binks, B. P., & Clint, J. H.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-01-18
- Volume
- 18
- Issue
- 4
- Pages
- 1270-1273
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2074067370
- Cited by
- 678
- References
- 11
- FWCI
- 8.89
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
