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Formation Mechanism of Self-Assembled Polyaniline Micro/Nanotubes
Abstract
Self-assembled micro/nanotubes (650−76 nm in diameter) of polyaniline (PANI) were synthesized in the presence of β-naphthalene sulfonic acid (β-NSA) as a dopant. It was found that the diameter and room-temperature conductivity of the PANI−NSA tubes decreased with the decrease of the molar ratio of β-NSA to aniline. On the bases of the results obtained from X-ray diffraction (XRD) and dynamic lighting scattering (DLS), it was proposed that when the molar ratio of β-NSA to aniline was high (e. g. 2), the NSA−An salt precipitate formed by β-NSA and aniline played a “template-like” role in forming the PANI−NSA tubes, while the “template-like” role was played by the NSA−An micelle when the ratio is low (e.g., 1 / 2 or 1 / 4 ).
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Cited by
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Stejskal, J., Sapurina, I., & Trchová, M. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2010.07.006 · Cited by 799
One dimensional nanostructured materials
Kuchibhatla, S. V. N. T., Karakoti, A. S., Bera, D., & Seal, S. (2007) · Progress in Materials Science · doi:10.1016/j.pmatsci.2006.08.001 · Cited by 631
Sapurina, I., & Stejskal, J. (2008) · Polymer International · doi:10.1002/pi.2476 · Cited by 580
Polyaniline Nanofibers Prepared by Dilute Polymerization
Chiou, N. ‐., & Epstein, A. J. (2005) · Advanced Materials · doi:10.1002/adma.200401000 · Cited by 562
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Li, D., & Kaner, R. B. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056609n · Cited by 548
Two-dimensional polyaniline (C 3 N) from carbonized organic single crystals in solid state
Mahmood, J., Lee, E. K., Jung, M., Shin, D., Choi, H.-J., Seo, J.-M., Jung, S.-M., Kim, D., Li, F., Lah, M. S., et al. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1605318113 · Cited by 478
Conducting Polymer Nanomaterials and Their Applications
Jang, J. (2006) · Advances in Polymer Science · doi:10.1007/12_075 · Cited by 425
The intrinsic nanofibrillar morphology of polyaniline
Huang, J., & Kaner, R. B. (2006) · Chem. Commun. · doi:10.1039/b510956f · Cited by 419
Polyaniline: Synthesis, properties, and application
Boeva, Z. A., & Sergeyev, V. G. (2014) · Polymer Science Series C · doi:10.1134/s1811238214010032 · Cited by 395
Metadata
- Authors
- Wei, Z., Zhang, Z., & Wan, M.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-01-10
- Volume
- 18
- Issue
- 3
- Pages
- 917-921
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W1992267536
- Cited by
- 505
- References
- 0
- FWCI
- 28.24
- Type
- journal article
- Language
- en
- Open access
- closed
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