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Two-dimensional polyaniline (C 3 N) from carbonized organic single crystals in solid state
Open accessAbstract
Significance: Two-dimensional (2D) polyaniline (PANI) has been realized for the first time, to our knowledge, by direct solid-state reaction of organic single crystals. The 2D PANI framework consists of six nitrogen atoms that periodically surround a phenyl ring. Pristine 2D PANI (undoped) has electrical conductivity of 0.72 S/cm, which is 10 10 times higher than its linear analog (undoped, 6.28 × 10 −11 S/cm). When it is doped by hydrochloric acid (HCl), its conductivity jumps to almost 1,960 times (1.41 × 10 3 S/cm). Due to its highest conductivity among organic materials, we very strongly believe that this well-defined 2D PANI and its heterogeneity with C and N elements will open up a new research field of layered 2D materials beyond linear PANI and other organic/inorganic 2D materials.
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Trends in Solid Adsorbent Materials Development for CO 2 Capture
Pardakhti, M., Jafari, T., Tobin, Z., Dutta, B., Moharreri, E., Shemshaki, N. S., Suib, S., & Srivastava, R. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b08487 · Cited by 357
Metadata
- Authors
- Mahmood, J., Lee, E. K., Jung, M., Shin, D., Choi, H.-J., Seo, J.-M., Jung, S.-M., Kim, D., Li, F., Lah, M. S., Park, N., Shin, H.-J., Oh, J. H., & Baek, J.-B.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2016-06-16
- Volume
- 113
- Issue
- 27
- Pages
- 7414-7419
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W2429669491
- Cited by
- 478
- References
- 25
- FWCI
- 29.69
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Mahmood, J., Lee, E. K., Jung, M., Shin, D., Choi, H.-J., Seo, J.-M., Jung, S.-M., Kim, D., Li, F., Lah, M. S., Park, N., Shin, H.-J., Oh, J. H., & Baek, J.-B. (2016). Two-dimensional polyaniline (C 3 N) from carbonized organic single crystals in solid state. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1605318113
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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