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Electrospun Poly(Styrene-block-dimethylsiloxane) Block Copolymer Fibers Exhibiting Superhydrophobicity
Abstract
Block copolymer poly(styrene-b-dimethylsiloxane) fibers with submicrometer diameters in the range 150-400 nm were produced by electrospinning from solution in tetrahydrofuran and dimethylformamide. Contact angle measurements indicate that the nonwoven fibrous mats are superhydrophobic, with a contact angle of 163 degrees and contact angle hysteresis of 15 degrees . The superhydrophobicity is attributed to the combined effects of surface enrichment in siloxane as revealed by X-ray photoelectron spectroscopy and surface roughness of the electrospun mat itself. Additionally, the fibers are shown by transmission electron microscopy to exhibit microphase-separated internal structures. Calorimetric studies confirm the strong segregation between the polystyrene and poly(dimethylsiloxane) blocks.
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Metadata
- Authors
- Ma, M., Hill, R. M., Lowery, J. L., Fridrikh, S. V., & Rutledge, G. C.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-04-30
- Volume
- 21
- Issue
- 12
- Pages
- 5549-5554
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2076271218
- Cited by
- 494
- References
- 50
- FWCI
- 15.19
- Type
- journal article
- Language
- en
- Open access
- closed
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