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Rheological Behavior of Water-in-Oil Emulsions Stabilized by Hydrophobic Bentonite Particles
Abstract
A study of the rheological behavior of water-in-oil emulsions stabilized by hydrophobic bentonite particles is described. Concentrated emulsions were prepared and diluted at constant particle concentration to investigate the effect of drop volume fraction on the viscosity and viscoelastic response of the emulsions. The influence of the structure of the hydrophobic clay particles in the oil has also been studied by using oils in which the clay swells to very different extents. Emulsions prepared from isopropyl myristate, in which the particles do not swell, are increasingly flocculated as the drop volume fraction increases and the viscosity of the emulsions increases accordingly. The concentrated emulsions are viscoelastic and the elastic storage and viscous loss moduli also increase with increasing drop volume fraction. Emulsions prepared from toluene, in which the clay particles swell to form tactoids, are highly structured due to the formation of an integrated network of clay tactoids and drops, and the moduli of the emulsions are significantly larger than those of the emulsions prepared from isopropyl myristate.
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Cited by
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Minas, C., Carnelli, D., Tervoort, E., & Studart, A. R. (2016) · Advanced Materials · doi:10.1002/adma.201603390 · Cited by 507
Oil-in-water emulsions stabilized by chitin nanocrystal particles
Tzoumaki, M. V., Moschakis, T., Kiosseoglou, V., & Biliaderis, C. G. (2011) · Food Hydrocolloids · doi:10.1016/j.foodhyd.2011.02.008 · Cited by 506
Comparison of solid particles, globular proteins and surfactants as emulsifiers
Tcholakova, S., Denkov, N. D., & Lips, A. (2008) · Physical Chemistry Chemical Physics · doi:10.1039/b715933c · Cited by 498
Torres, L. G., Iturbe, R., Snowden, M. J., Chowdhry, B. Z., & Leharne, S. A. (2007) · Colloids and Surfaces A: Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2007.03.009 · Cited by 275
Perino, A., Noïk, C., & Dalmazzone, C. (2013) · Energy & Fuels · doi:10.1021/ef301627e · Cited by 36
Metadata
- Authors
- Binks, B. P., Clint, J. H., & Whitby, C. P.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-05-10
- Volume
- 21
- Issue
- 12
- Pages
- 5307-5316
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2069370375
- Cited by
- 161
- References
- 0
- FWCI
- 2.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- Binks, B. P., Clint, J. H., & Whitby, C. P. (2005). Rheological Behavior of Water-in-Oil Emulsions Stabilized by Hydrophobic Bentonite Particles. Langmuir. https://doi.org/10.1021/la050255w
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