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Importance of Structural and Chemical Heterogeneity of Activated Carbon Surfaces for Adsorption of Dibenzothiophene
Abstract
The performance of various activated carbons obtained from different carbon precursors (i.e., plastic waste, coal, and wood) as adsorbents for the desulfurization of liquid hydrocarbon fuels was evaluated. To increase surface heterogeneity, the carbon surface was modified by oxidation with ammonium persulfate. The results showed the importance of activated carbon pore sizes and surface chemistry for the adsorption of dibenzothiophene (DBT) from liquid phase. Adsorption of DBT on activated carbons is governed by two types of contributions: physical and chemical interactions. The former include dispersive interactions in the microporous network of the carbons. While the volume of micropores governs the amount physisorbed, mesopores control the kinetics of the process. On the other hand, introduction of surface functional groups enhances the performance of the activated carbons as a result of specific interactions between the acidic centers of the carbon and the basic structure of DBT molecule as well as sulfur-sulfur interactions.
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On a theory of the van der waals adsorption of gases
Brunauer, S., Deming, L. S., Deming, W. E., & Teller, E. (1940) · Journal of the American Chemical Society · doi:10.1021/ja01864a025 · Cited by 4,829
Cited by
Pi, Y., Li, X., Xia, Q., Wu, J., Li, Y., Xiao, J., & Li, Z. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.12.092 · Cited by 549
Liquid Phase Adsorption by Microporous Coordination Polymers: Removal of Organosulfur Compounds
Cychosz, K. A., Wong-Foy, A. G., & Matzger, A. J. (2008) · Journal of the American Chemical Society · doi:10.1021/ja802121u · Cited by 391
Carbonized Eggshell Membrane as a Natural Polysulfide Reservoir for Highly Reversible Li‐S Batteries
Chung, S., & Manthiram, A. (2014) · Advanced Materials · doi:10.1002/adma.201304365 · Cited by 375
Enabling Cleaner Fuels: Desulfurization by Adsorption to Microporous Coordination Polymers
Cychosz, K. A., Wong-Foy, A. G., & Matzger, A. J. (2009) · Journal of the American Chemical Society · doi:10.1021/ja906034k · Cited by 255
Carbonization: A feasible route for reutilization of plastic wastes
Chen, S., Liu, Z., Jiang, S., & Hou, H. (2020) · Science of The Total Environment · doi:10.1016/j.scitotenv.2019.136250 · Cited by 213
Metadata
- Authors
- Ania, C. O., & Bandosz, T. J.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-07-19
- Volume
- 21
- Issue
- 17
- Pages
- 7752-7759
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2007471871
- Cited by
- 227
- References
- 1
- FWCI
- 15.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ania, C. O., & Bandosz, T. J. (2005). Importance of Structural and Chemical Heterogeneity of Activated Carbon Surfaces for Adsorption of Dibenzothiophene. Langmuir. https://doi.org/10.1021/la050772e
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