The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Grafting from Surfaces for “Everyone”: ARGET ATRP in the Presence of Air
Abstract
Atom-transfer radical polymerization (ATRP) is one of the controlled/living radical polymerizations yielding well-defined (co)polymers, nanocomposites, molecular hybrids, and bioconjugates. ATRP, as in any radical process, has to be carried out in rigorously deoxygenated systems to prevent trapping of propagating radicals by oxygen. Herein, we report that ATRP can be performed in the presence of limited amount of air and with a very small (typically ppm) amount of copper catalyst together with an appropriate reducing agent. This technique has been successfully applied to the preparation of densely grafted polymer brushes, poly(n-butyl acrylate) homopolymer, and poly(n-butyl acrylate)-block-polystyrene copolymer from silicon wafers (0.4 chains/nm2). This simple new method of grafting well-defined polymers does not require any special equipment and can be carried out in vials or jars without deoxygenation. The grafting for "everyone" technique is especially useful for wafers and other large objects and may be also applied for molecular hybrids and bioconjugates.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
The convergence of synthetic organic and polymer chemistries
Hawker, C. J., & Wooley, K. L. (2005) · Science · doi:10.1126/science.1109778 · Cited by 1,298
Cited by
Barbey, R., Lavanant, L., Paripovic, D., Schüwer, N., Sugnaux, C., Tugulu, S., & Klok, H.-A. (2009) · Chemical Reviews · doi:10.1021/cr900045a · Cited by 1,753
Ouchi, M., Terashima, T., & Sawamoto, M. (2009) · Chemical Reviews · doi:10.1021/cr900234b · Cited by 1,257
Electrochemically Mediated Atom Transfer Radical Polymerization
Magenau, A. J. D., Strandwitz, N. C., Gennaro, A., & Matyjaszewski, K. (2011) · Science · doi:10.1126/science.1202357 · Cited by 804
Self-citationMurata, H., Koepsel, R. R., Matyjaszewski, K., & Russell, A. J. (2007) · Biomaterials · doi:10.1016/j.biomaterials.2007.06.012 · Cited by 722
Self-citationAtrp in the design of functional materials for biomedical applications
Siegwart, D. J., Oh, J. K., & Matyjaszewski, K. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.08.001 · Cited by 613
Self-citationHui, C. M., Pietrasik, J., Schmitt, M., Mahoney, C., Choi, J., Bockstaller, M. R., & Matyjaszewski, K. (2014) · Chemistry of Materials · doi:10.1021/cm4023634 · Cited by 367
Self-citationHuang, J., Koepsel, R. R., Murata, H., Wu, W., Lee, S. B., Kowalewski, T., Russell, A. J., & Matyjaszewski, K. (2008) · Langmuir · doi:10.1021/la8003933 · Cited by 231
Self-citationArget atrp of methyl methacrylate in the presence of nitrogen-based ligands as reducing agents
Kwak, Y., & Matyjaszewski, K. (2009) · Polymer International · doi:10.1002/pi.2530 · Cited by 159
Self-citation
Metadata
- Authors
- Matyjaszewski, K., Dong, H., Jakubowski, W., Pietrasik, J., & Kusumo, A.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-03-20
- Volume
- 23
- Issue
- 8
- Pages
- 4528-4531
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2008512441
- Cited by
- 682
- References
- 1
- FWCI
- 15.37
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
