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The DOI matches its Crossref record; 25 of the 25 references it cites were found in a registry or an index.

Self-Assembly of Cationic Polyelectrolyte-Functionalized Graphene Nanosheets and Gold Nanoparticles: A Two-Dimensional Heterostructure for Hydrogen Peroxide Sensing

Fang, Youxing, Guo, Shaojun, Zhu, Chengzhou, Zhai, Yueming, Wang, Erkang·2010·Langmuir

Abstract

We demonstrate the use of cationic polyelectrolyte poly(diallyldimethyl ammonium chloride) (PDDA) functionalized graphene nanosheets (GNs) as the building block in the self-assembly of GNs/Au nanoparticles (NPs) heterostructure to enhance the electrochemical catalytic ability. To ensure the GNs were modified with PDDA successfully, we study the PDDA/GNs with atomic force microscopy (AFM) and zeta potential measurements on the roughness and zeta potential changes relative to those of unmodified GNs, respectively. Then, the citrate-capped Au NPs are employed as the other model particles to construct two-dimensional GNs/NPs heterostructure. Here, the use of PDDA modifiers not only alters the electrostatic charges of graphene, but also probably provides a convenient self-assembly approach to the hybridization of graphene. Furthermore, we employ the high-loading Au NPs on graphene (GN/Au-NPs) as the electrochemical enhanced material for H(2)O(2) sensing (as the model analyte). The wide linear ranges and low detection limits are obtained using the chronoamperometry technique at the GN/Au-NPs-modified glassy carbon electrode.

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Metadata

Authors
Fang, Y., Guo, S., Zhu, C., Zhai, Y., & Wang, E.
Venue
Langmuir
Published
2010-03-16
Volume
26
Issue
13
Pages
11277-11282
ISSN
  • 0743-7463 (ISSN-L)
  • 1520-5827
OpenAlex
W2078008632
Cited by
321
References
25
FWCI
28.91
Type
journal article
Language
en
Open access
closed

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Fang, Y., Guo, S., Zhu, C., Zhai, Y., & Wang, E. (2010). Self-Assembly of Cationic Polyelectrolyte-Functionalized Graphene Nanosheets and Gold Nanoparticles: A Two-Dimensional Heterostructure for Hydrogen Peroxide Sensing. Langmuir. https://doi.org/10.1021/la100575g

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