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Self-Assembled TiO2–Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion
Abstract
We used anionic sulfate surfactants to assist the stabilization of graphene in aqueous solutions and facilitate the self-assembly of in situ grown nanocrystalline TiO2, rutile and anatase, with graphene. These nanostructured TiO2-graphene hybrid materials were used for investigation of Li-ion insertion properties. The hybrid materials showed significantly enhanced Li-ion insertion/extraction in TiO2. The specific capacity was more than doubled at high charge rates, as compared with the pure TiO2 phase. The improved capacity at high charge-discharge rate may be attributed to increased electrode conductivity in the presence of a percolated graphene network embedded into the metal oxide electrodes.
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Cites
Electric Field Effect in Atomically Thin Carbon Films
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V., & Firsov, A. A. (2004) · Science · doi:10.1126/science.1102896 · Cited by 66,834
Graphene-based composite materials
Stankovich, S., Dikin, D. A., Dommett, G. H. B., Kohlhaas, K. M., Zimney, E. J., Stach, E. A., Piner, R. D., Nguyen, S. T., & Ruoff, R. S. (2006) · Nature · doi:10.1038/nature04969 · Cited by 12,922
Cited by
Graphene-based semiconductor photocatalysts
Xiang, Q., Yu, J., & Jaroniec, M. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15172j · Cited by 2,730
Wang, H., Yang, Y., Liang, Y., Robinson, J. T., Li, Y., Jackson, A., Cui, Y., & Dai, H. (2011) · Nano Letters · doi:10.1021/nl200658a · Cited by 2,119
Ni(OH) 2 Nanoplates Grown on Graphene as Advanced Electrochemical Pseudocapacitor Materials
Wang, H., Casalongue, H. S., Liang, Y., & Dai, H. (2010) · Journal of the American Chemical Society · doi:10.1021/ja102267j · Cited by 2,042
Energy storage: The future enabled by nanomaterials
Pomerantseva, E., Bonaccorso, F., Feng, X., Cui, Y., & Gogotsi, Y. (2019) · Science · doi:10.1126/science.aan8285 · Cited by 1,927
Synthesis Of Nitrogen-Doped Graphene Films For Lithium Battery Application
Reddy, A. L. M., Srivastava, A., Gowda, S. R., Gullapalli, H., Dubey, M., & Ajayan, P. M. (2010) · ACS Nano · doi:10.1021/nn101926g · Cited by 1,642
Metadata
- Authors
- Wang, D., Choi, D., Li, J., Yang, Z., Nie, Z., Kou, R., Hu, D., Wang, C., Saraf, L. V., Zhang, J., Aksay, I. A., & Liu, J.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-26
- Volume
- 3
- Issue
- 4
- Pages
- 907-914
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2094070298
- Cited by
- 1,654
- References
- 2
- FWCI
- 126.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, D., Choi, D., Li, J., Yang, Z., Nie, Z., Kou, R., Hu, D., Wang, C., Saraf, L. V., Zhang, J., Aksay, I. A., & Liu, J. (2009). Self-Assembled TiO2–Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion. ACS Nano. https://doi.org/10.1021/nn900150y
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