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The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

Polyaniline-Functionalized Carbon Nanotube Supported Platinum Catalysts

He, Daping, Zeng, Chao, Xu, Cheng, Cheng, Niancai, Li, Huaiguang, Mu, Shichun, Pan, Mu·2011·Langmuir

Abstract

Electrocatalytically active platinum (Pt) nanoparticles on a carbon nanotube (CNT) with enhanced nucleation and stability have been demonstrated through introduction of electron-conducting polyaniline (PANI) to bridge the Pt nanoparticles and CNT walls with the presence of platinum-nitride (Pt-N) bonding and π-π bonding. The Pt colloids were prepared through ethanol reduction under the protection of aniline, the CNT was dispersed well with the existence of aniline in the solution, and aniline was polymerized in the presence of a protonic acid (HCl) and an oxidant (NH(4)S(2)O(8)). The synthesized PANI is found to wrap around the CNT as a result of π-π bonding, and highly dispersed Pt nanoparticles are loaded onto the CNT with narrowly distributed particle sizes ranging from 2.0 to 4.0 nm due to the polymer stabilization and existence of Pt-N bonding. The Pt-PANI/CNT catalysts are electroactive and exhibit excellent electrochemical stability and therefore promise potential applications in proton exchange membrane fuel cells.

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Metadata

Authors
He, D., Zeng, C., Xu, C., Cheng, N., Li, H., Mu, S., & Pan, M.
Venue
Langmuir
Published
2011-04-08
Volume
27
Issue
9
Pages
5582-5588
ISSN
  • 0743-7463 (ISSN-L)
  • 1520-5827
OpenAlex
W2314490291
Cited by
255
References
3
FWCI
9.46
Type
journal article
Language
en
Open access
closed

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