The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Graphene Supported Co-g-C3N4 as a Novel Metal–Macrocyclic Electrocatalyst for the Oxygen Reduction Reaction in Fuel Cells
Abstract
Graphitic carbon nitride (g-C3N4) polymer was doped with cobalt species and supported on a similar sp(2) structure graphene, to form a novel nitrogen-metal macrocyclic catalyst for the oxygen reduction reaction (ORR) in alkaline fuel cells. The structural characterizations confirmed the formation of Co-N bonds and the close electron coupling between Co-g-C3N4 and graphene sheets. The electrocatalytic measurements demonstrated Co-g-C3N4-catalyzed reduction of oxygen mainly in a four electron pathway. The improvement of ORR activity is closely related to the abundant accessible Co-Nx active sites and fast charge transfer at the interfaces of Co-g-C3N4/graphene. Also, Co-g-C3N4@graphene exhibited comparable ORR activity, better durability, and methanol tolerance ability in comparison to Pt/C, and bodes well for a promising non-noble cathode catalyst for the application of direct methanol fuel cells. The chemical doping strategy in this work would be helpful to improve other present catalysts for fuel cell applications.
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Yang, S., Feng, X., Wang, X., & Müllen, K. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201100170 · Cited by 1,109
Cui, Y., Ding, Z., Liu, P., Antonietti, M., Fu, X., & Wang, X. (2012) · Phys. Chem. Chem. Phys. · doi:10.1039/c1cp22820j · Cited by 585
Cited by
Zheng, Y., Jiao, Y., Zhu, Y., Cai, Q., Vasileff, A., Li, L. H., Han, Y., Chen, Y., & Qiao, S.-Z. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13100 · Cited by 1,250
Dong, G., Zhang, Y., Pan, Q., & Qiu, J. (2014) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2014.04.002 · Cited by 1,085
Interacting Carbon Nitride and Titanium Carbide Nanosheets for High‐Performance Oxygen Evolution
Ma, T. Y., Cao, J. L., Jaroniec, M., & Qiao, S. Z. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201509758 · Cited by 733
Sharma, R. K., Yadav, P., Yadav, M., Gupta, R., Rana, P., Srivastava, A., Zbořil, R., Varma, R. S., Antonietti, M., & Gawande, M. B. (2020) · Materials Horizons · doi:10.1039/c9mh00856j · Cited by 455
2D Graphitic Carbon Nitride for Energy Conversion and Storage
Wang, Y., Liu, L., Ma, T., Zhang, Y., & Huang, H. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202102540 · Cited by 448
Metadata
- Authors
- Liu, Q., & Zhang, J.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-03-08
- Volume
- 29
- Issue
- 11
- Pages
- 3821-3828
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2328025663
- Cited by
- 418
- References
- 2
- FWCI
- 15.87
- Type
- journal article
- Language
- en
- Open access
- closed
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