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Cited by 269

The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.

Superhydrophobic Composite Films Produced on Various Substrates

Manoudis, Panagiotis N., Karapanagiotis, Ioannis, Tsakalof, Andreas, Zuburtikudis, Ioannis, Panayiotou, Costas·2008·Langmuir

Abstract

Hydrophilic silica (SiO2) nanoparticles were dispersed in solutions of poly(methyl methacrylate) (PMMA) and in solutions of a commercial poly(alkyl siloxane) (Rhodorsil 224), and the suspensions were sprayed on glass surfaces. The effect of the particle concentration on the hydrophobic character of PMMA-SiO2 and Rhodorsil-SiO2 films was investigated and showed the following: (i) Static contact angles (theta s), measured on surfaces that were prepared from dilute dispersions (particle concentration <1% w/v), increase rapidly with particle concentration and reach maximum values (154 and 164 degrees for PMMA-SiO2 and siloxane-SiO2, respectively). Further increases in particle concentration do not have any effect on theta s. (ii) The effect of particle concentration on the contact angle hysteresis (thetaAlpha - thetaR) is more complicated: as the particle concentration increases, we first notice an increase in hysteresis, which then decreases and finally becomes constant at elevated particle concentrations. The lowest thetaAlpha - thetaR values were 5 degrees for PMMA-SiO2 and 3 degrees for siloxane-SiO2, respectively. (iii) SEM and AFM images show that a two-length-scale hierarchical structure is formed on the surface of the superhydrophobic films. It is demonstrated that superhydrophobicity can be achieved using various hydrophilic nanoparticles (alumina and tin oxide nanoparticles were successfully tested) and that the substrate has almost no effect on the hydrophobic character of the applied coatings, which were produced on silicon, concrete, aluminum, silk, wood, marble, and of course glass. The results are discussed in light of Wenzel and Cassie-Baxter models.

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Metadata

Authors
Manoudis, P. N., Karapanagiotis, I., Tsakalof, A., Zuburtikudis, I., & Panayiotou, C.
Venue
Langmuir
Published
2008-08-23
Volume
24
Issue
19
Pages
11225-11232
ISSN
  • 0743-7463 (ISSN-L)
  • 1520-5827
OpenAlex
W2066687040
Cited by
269
References
29
FWCI
8.00
Type
journal article
Language
en
Open access
closed

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