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Cited by 398

The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.

Calorimetric Heats of Adsorption and Adsorption Isotherms. 1. O2, N2, Ar, CO2, CH4, C2H6, and SF6 on Silicalite

Dunne, J. A., Mariwala, R., Rao, M., Sircar, S., Gorte, R. J., Myers, A. L.·1996·Langmuir

Abstract

A Tian−Calvet type calorimeter is applied to the simultaneous determination of adsorption isotherms and heats of adsorption. This is the first of a series of studies of the effect of adsorbate size and polarity on the energetics of adsorption in zeolites. The adsorbate gases used in this study are quadrupolar (N 2 and CO 2 ) and nonpolar (Ar, O 2, CH 4, C 2 H 6, and SF 6 ). The heats of adsorption of both polar and nonpolar gases are either constant or increase with coverage, so silicalite may be classified as a relatively homogeneous adsorbent compared to X type zeolite. Reversibility was established by comparing adsorption and desorption isotherms. Reproducibility was studied by comparing runs for different samples of the same adsorbent. The average experimental error in loading is ±0.6%. The error in the isosteric heat of adsorption is ±2% for heats larger than 20 kJ/mol and ±5% for heats smaller than 20 kJ/mol.

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Metadata

Authors
Dunne, J. A., Mariwala, R., Rao, M., Sircar, S., Gorte, R. J., & Myers, A. L.
Venue
Langmuir
Published
1996-01-01
Volume
12
Issue
24
Pages
5888-5895
ISSN
  • 0743-7463 (ISSN-L)
  • 1520-5827
OpenAlex
W1966428762
Cited by
398
References
7
FWCI
5.81
Type
journal article
Language
en
Open access
closed

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