The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.
Directing Oleate Stabilized Nanosized Silver Colloids into Organic Phases
Abstract
Nanosized hydrophobic, oleate stabilized silver organosols in various organic solvents are obtained using a solvent exchange method. The silver particles are initially prepared as a hydrosol in the presence of sodium oleate (surfactant). Then a transfer of the colloid to an organic phase is induced by a low concentration of several agents such as orthophosphoric acid, with a transfer efficiency of 50−70%. The hydrophobic colloid is stable and the particles retain their integrity even after the solvent is evaporated and the dried deposit is resuspended in a variety of other solvents. We present the preparation method in detail and characterize the hydrosol and organosol particles by electron microscopy, electrophoresis, and UV−visible extinction spectroscopy. On the basis of IR spectroscopy we discuss the conformation of the surfactant adsorbed on the silver cores and the changes in it as the particles transfer into the organic environment.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Murray, C. B., Norris, D. J., & Bawendi, M. G. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00072a025 · Cited by 9,282
Synthesis of thiol-derivatised gold nanoparticles in a two-phase Liquid–Liquid system
Brust, M., Walker, M., Bethell, D., Schiffrin, D. J., & Whyman, R. (1994) · J. Chem. Soc., Chem. Commun. · doi:10.1039/c39940000801 · Cited by 6,707
The Infra-red Spectra of Complex Molecules
Bellamy, L. J. (1975) · Springer eBooks · doi:10.1007/978-94-011-6017-9 · Cited by 5,807
Introduction to Infrared and Raman Spectroscopy
(1975) · Elsevier eBooks · doi:10.1016/b978-0-12-182552-2.x5001-3 · Cited by 5,474
Surface Plasmon Spectroscopy of Nanosized Metal Particles
Mulvaney, P. (1996) · Langmuir · doi:10.1021/la9502711 · Cited by 3,681
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
Self-Organization of CdSe Nanocrystallites into Three-Dimensional Quantum Dot Superlattices
Murray, C. B., Kagan, C. R., & Bawendi, M. G. (1995) · Science · doi:10.1126/science.270.5240.1335 · Cited by 2,220
Large clusters and colloids. Metals in the embryonic state
Schmid, G. (1992) · Chemical Reviews · doi:10.1021/cr00016a002 · Cited by 1,867
Henglein, A. (1993) · The Journal of Physical Chemistry · doi:10.1021/j100123a004 · Cited by 1,726
Creighton, J. A., Blatchford, C. G., & Albrecht, M. G. (1979) · Journal of the Chemical Society, Faraday Transactions 2 · doi:10.1039/f29797500790 · Cited by 1,694
Ultraviolet–visible absorption spectra of the colloidal metallic elements
Creighton, J. A., & Eadon, D. G. (1991) · J. Chem. Soc., Faraday Trans. · doi:10.1039/ft9918703881 · Cited by 1,625
Chemical catalysis by colloids and clusters
Lewis, L. N. (1993) · Chemical Reviews · doi:10.1021/cr00024a006 · Cited by 1,438
Weller, H. (1993) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199300411 · Cited by 1,271
Nanochemistry: Synthesis in diminishing dimensions
Ozin, G. A. (1992) · Advanced Materials · doi:10.1002/adma.19920041003 · Cited by 1,267
Leff, D. V., Brandt, L., & Heath, J. R. (1996) · Langmuir · doi:10.1021/la960445u · Cited by 924
Terrill, R. H., Postlethwaite, T. A., Chen, C.-H., Poon, C.-D., Terzis, A., Chen, A., Hutchison, J. E., Clark, M. R., & Wignall, G. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00155a017 · Cited by 853
The Colloid Chemical Approach to Nanostructured Materials**
Fendler, J. H., & Meldrum, F. C. (1995) · Advanced Materials · doi:10.1002/adma.19950070703 · Cited by 722
In situ synthesis of silver nanocluster in AOT reverse micelles
Petit, C., Lixon, P., & Pileni, M. P. (1993) · The Journal of Physical Chemistry · doi:10.1021/j100151a054 · Cited by 693
Thermodynamic Control of Gold Nanocrystal Size: Experiment and Theory
Leff, D. V., Ohara, P. C., Heath, J. R., & Gelbart, W. M. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100018a041 · Cited by 661
Preparation of ordered colloid monolayers by electrophoretic deposition
Giersig, M., & Mulvaney, P. (1993) · Langmuir · doi:10.1021/la00036a014 · Cited by 646
Pieranski, P. (1983) · Contemporary Physics · doi:10.1080/00107518308227471 · Cited by 634
Taleb, A., Petit, C., & Pileni, M. P. (1997) · Chemistry of Materials · doi:10.1021/cm960513y · Cited by 557
Heath, J. R., Knobler, C. M., & Leff, D. V. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp9611582 · Cited by 536
Silver Clusters and Chemistry in Zeolites
Sun, T., & Seff, K. (1994) · Chemical Reviews · doi:10.1021/cr00028a001 · Cited by 418
Crystallization of Opals from Polydisperse Nanoparticles
Ohara, P. C., Leff, D. V., Heath, J. R., & Gelbart, W. M. (1995) · Physical Review Letters · doi:10.1103/physrevlett.75.3466 · Cited by 384
Highly Oriented Molecular Ag Nanocrystal Arrays
Harfenist, S. A., Wang, Z. L., Alvarez, M. M., Vezmar, I., & Whetten, R. L. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp961764x · Cited by 381
Reduction and Stabilization of Silver Nanoparticles in Ethanol by Nonionic Surfactants
Liz-Marzán, L. M., & Lado-Touriño, I. (1996) · Langmuir · doi:10.1021/la951501e · Cited by 315
The optics of colloidal silver: something old and something new
Kerker, M. (1985) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(85)90304-2 · Cited by 314
Langmuir-Blodgett Manipulation of Size-Selected CdSe Nanocrystallites
Dabbousi, B. O., Murray, C. B., Rubner, M. F., & Bawendi, M. G. (1994) · Chemistry of Materials · doi:10.1021/cm00038a020 · Cited by 285
Toshima, N., Yonezawa, T., & Kushihashi, K. (1993) · J. Chem. Soc., Faraday Trans. · doi:10.1039/ft9938902537 · Cited by 284
Control of the Shape of Copper Metallic Particles by Using a Colloidal System as Template
Tanori, J., & Pileni, M. P. (1997) · Langmuir · doi:10.1021/la9606097 · Cited by 274
The “New” Science of “Complex Fluids”
Gelbart, W. M., & Ben-Shaul, A. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9606570 · Cited by 270
Self-Assembled Monolayer of Nanosized Particles Differing by Their Sizes
Motte, L., Billoudet, F., & Pileni, M. P. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100044a033 · Cited by 269
Spectroelectrochemistry of Colloidal Silver
Ung, T., Giersig, M., Dunstan, D., & Mulvaney, P. (1997) · Langmuir · doi:10.1021/la960863z · Cited by 257
Stable hydrosols of metallic and bimetallic nanoparticles immobilized on imogolite fibers
Liz-Marzan, L. M., & Philipse, A. P. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100041a031 · Cited by 246
Self-Organization into 2D and 3D Superlattices of Nanosized Particles Differing by Their Size
Motte, L., Billoudet, F., Lacaze, E., Douin, J., & Pileni, M. P. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp962398k · Cited by 232
Esumi, K., Tano, T., Torigoe, K., & Meguro, K. (1990) · Chemistry of Materials · doi:10.1021/cm00011a019 · Cited by 202
The characterization of ag sols by electron microscopy, optical absorption, and electrophoresis
Heard, S. M., Grieser, F., Barraclough, C. G., & Sanders, J. V. (1983) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(83)90439-3 · Cited by 200
Ordered aggregates of ultrafine iron oxide particles: ‘Super crystals’
Bentzon, M. D., van Wonterghem, J., Mørup, S., Thölén, A., & Koch, C. J. W. (1989) · Philosophical Magazine B · doi:10.1080/13642818908211188 · Cited by 179
Bahnemann, D. W. (1993) · Israel Journal of Chemistry · doi:10.1002/ijch.199300017 · Cited by 171
Charlé, K. ‐., Frank, F., & Schulze, W. (1984) · Berichte der Bunsengesellschaft für physikalische Chemie · doi:10.1002/bbpc.19840880407 · Cited by 148
Vibrational spectroscopic study on polymorphism and order-disorder phase transition in oleic acid
Kobayashi, M., Kaneko, F., Sato, K., et al. (1986) · The Journal of Physical Chemistry · doi:10.1021/j100281a062 · Cited by 145
The Complexation of Gold Colloids
Schmid, G., & Lehnert, A. (1989) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198907801 · Cited by 135
Kimura, K., & Bandow, S. (1983) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.56.3578 · Cited by 86
COLLOIDAL RHODIUM IN POLY(VINYLPYRROLIDONE) AS HYDROGENATION CATALYST FOR INTERNAL OLEFINS
Hirai, H., Nakao, Y., & Toshima, N. (1978) · Chemistry Letters · doi:10.1246/cl.1978.545 · Cited by 83
Satoh, N., & Kimura, K. (1989) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.62.1758 · Cited by 67
Ligand stabilized nickel colloids
Duteil, A., Schmid, G., & Meyer‐Zaika, W. (1995) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39950000031 · Cited by 46
Synthesis “in situ” of nanoparticles in reverse micelles
Pileni, M. P., Lisiecki, I., Motte, L., Petit, C., Cizeron, J., Moumen, N., & Lixon, P. (2008) · Steinkopff eBooks · doi:10.1007/bfb0118461 · Cited by 40
Preparation of Nonaqueous Dispersion of Colloidal Silver by Phase Transfer
Hirai, H., Aizawa, H., & Shiozaki, H. (1992) · Chemistry Letters · doi:10.1246/cl.1992.1527 · Cited by 33
Phase contrast from a regular stacking of equally sized iron-oxide spheres
Bentzon, M. D., & Thölén, A. R. (1991) · Ultramicroscopy · doi:10.1016/0304-3991(91)90111-i · Cited by 32
Cited by
Hegmann, T., Qi, H., & Marx, V. M. (2007) · Journal of Inorganic and Organometallic Polymers and Materials · doi:10.1007/s10904-007-9140-5 · Cited by 396
Efficient fuel cell catalysts emerging from organometallic chemistry
Bönnemann, H., & Khelashvili, G. (2010) · Applied Organometallic Chemistry · doi:10.1002/aoc.1613 · Cited by 30
Metadata
- Authors
- Wang, W., Efrima, S., & Regev, O.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-02-01
- Volume
- 14
- Issue
- 3
- Pages
- 602-610
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2069539399
- Cited by
- 255
- References
- 50
- FWCI
- 7.54
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.