Stratified Assemblies of Magnetite Nanoparticles and Montmorillonite Prepared by the Layer-by-Layer Assembly

Abstract

Hybrid thin films are prepared from 8 to 10 nm Fe 3 O 4 nanoparticles and exfoliated montmorillonite clay by using layer-by-layer assembly on poly(diallyldimethylammonium bromide), PDDA. Distinct stratification of the Fe 3 O 4 /PDDA/clay films is obtained due to the sheetlike structure of the clay particles. This feature distinguishes these assemblies from their polyelectrolyte−polyelectrolyte analogues, where the layers of individual polyelectrolytes are strongly interdigitated. Being adsorbed on PDDA strictly parallel to the substrate surface, montmorillonite produces a dense layer of overlapping alumosilicate sheets, which virtually flawlessly separates one magnetite layer from another. The difference in magnetic properties between assemblies of various architectures is attributed to the insulation effect of clay layers inserted between magnetic layers. The montmorillonite sheets disrupt the electron exchange interactions between the magnetite nanoparticles in adjacent layers, thereby limiting the magnetization reversal to two dimensions. Some optical properties of Fe 3 O 4 /PDDA films are investigated as well. When they are deposited on thin plastic substrate, oscillations of optical density were observed in the red part of the UV−vis spectrum. This effect, which was never been observed for conventional, thick substrates such as glass slides, stems from the interference of the light beams passed through and reflected off of the assembled film.