Poly[(aryloxy)carbophosphazenes]: Synthesis, properties, and thermal transition behavior
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPoly[(aryloxy)carbophosphazenes]: synthesis, properties, and thermal transition behaviorHarry R. Allcock, Suzanne M. Coley, Ian Manners, Oskar Nuyken, and Gerhard RennerCite this: Macromolecules 1991, 24, 8, 2024–2028Publication Date (Print):April 1, 1991Publication History Published online1 May 2002Published inissue 1 April 1991https://pubs.acs.org/doi/10.1021/ma00008a048https://doi.org/10.1021/ma00008a048research-articleACS PublicationsRequest reuse permissionsArticle Views203Altmetric-Citations49LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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The necessity of subsequent substitution of the -Cl groups and crosslinking during polymerization remain as disadvantages.
“but necessity of subsequent substitution of the -Cl groups and the crosslinking during polymerization remain as disadvantages [190 -192].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [191]
If one of the -PCl2 groups in the ring is exchanged for XCl, the ring strain can be increased and a ring-opening polymerization occurs at lower temperature.
“If one of the -PCl2-groups in the ring is exchanged for XCl (see Figure 67) the ring strain can be increased and a ring-opening polymerization occurs at lower temperature”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [191]
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“If one of the −PCl2-groups in the ring is exchanged for XCl (see Figure 67) the ring strain can be increased and a ring-opening polymerization occurs at lower temperature but necessity of subsequent substitution of the –Cl groups and the crosslinking during polymerization remain as disadvantages [190–192].”
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Jaeger, R. D. (1998) · Progress in Polymer Science · doi:10.1016/s0079-6700(97)00027-0 · Cited by 249 · see citing works
Manners, I. (1995) · Advances in organometallic chemistry · doi:10.1016/s0065-3055(08)60599-7 · Cited by 248 · see citing works
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Becker, G., & Wurm, F. R. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00531a · Cited by 229 · see citing works
Allcock, H. R. (1994) · Advanced Materials · doi:10.1002/adma.19940060203 · Cited by 200 · see citing works
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Self-citationNi, Y., Park, P., Liang, M., et al. (1996) · Macromolecules · doi:10.1021/ma951611s · Cited by 48 · see citing works
Self-citationThe First Sulfur( VI )–Nitrogen–Phosphorus Macrocycles
Ni, Y., Lough, A. J., Rheingold, A. L., et al. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199509981 · Cited by 46 · see citing works
Self-citationSulfur-nitrogen-phosphorus polymers
Manners, I. (1994) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(94)03001-7 · Cited by 39 · see citing works
Self-citationSingh, K. P., Mishra, A., Kumar, N., et al. (2017) · Polymer Bulletin · doi:10.1007/s00289-017-2156-2 · Cited by 35 · see citing works
Carriedo, G. A., Alonso, F. J. G., & González, P. A. (1997) · Macromolecular Rapid Communications · doi:10.1002/marc.1997.030180503 · Cited by 32 · see citing works
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Self-citationChandrasekhar, V., Arunachalampillai, A., Reddy, N. D., et al. (2002) · Inorganic Chemistry · doi:10.1021/ic025940u · Cited by 28 · see citing works
Zhao, Z., Guo, Q., Li, X., et al. (2012) · Journal of Applied Polymer Science · doi:10.1002/app.38650 · Cited by 26 · see citing works
Vij, A., Elias, A. J., Kirchmeier, R. L., et al. (1997) · Inorganic Chemistry · doi:10.1021/ic9612921 · Cited by 20 · see citing works
Bortolus, P., & Gleria, M. (1994) · Journal of Inorganic and Organometallic Polymers and Materials · doi:10.1007/bf00683716 · Cited by 19 · see citing works
Chandrasekhar, V., Azhakar, R., Venkatasubbaiah, K., et al. (2006) · Journal of the American Chemical Society · doi:10.1021/ja061635m · Cited by 19 · see citing works
Foucher, D. A., Lough, A. J., & Manners, I. (1991) · Journal of Organometallic Chemistry · doi:10.1016/0022-328x(91)83249-4 · Cited by 19 · see citing works
Self-citationLiang, M., & Manners, I. (1991) · Die Makromolekulare Chemie Rapid Communications · doi:10.1002/marc.1991.030121102 · Cited by 17 · see citing works
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Manners, I. (1992) · Annual Reports Section A (Inorganic Chemistry) · doi:10.1039/ic9928900093 · Cited by 9 · see citing works
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Chivers, T., Gates, D. P., Li, X., et al. (1998) · Inorganic Chemistry · doi:10.1021/ic9808652 · Cited by 8 · see citing works
Self-citationKoltzenburg, S., Maskos, M., & Nuyken, O. (2017) · Polymer Chemistry · doi:10.1007/978-3-662-49279-6_12 · Cited by 6 · see citing works
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Ni, Y., Lough, A. J., Rheingold, A. L., et al. (1995) · Angewandte Chemie · doi:10.1002/ange.19951070909 · Cited by 6 · see citing works
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Liang, M., Waddling, C., Honeyman, C. H., et al. (1992) · Phosphorus, sulfur, and silicon and the related elements · doi:10.1080/10426509208041136 · Cited by 5 · see citing works
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Dück, K., & Gates, D. P. (2017) · doi:10.1002/9781119235941.ch13 · Cited by 4 · see citing works
Rubber, 8. Synthesis by Polymer Modification
Happ, M., Duffy, J. J., Wilson, G. J., Pask, S. D., Buding, H., & Ostrowicki, A. (2011) · Ullmann's Encyclopedia of Industrial Chemistry · doi:10.1002/14356007.o23_o05 · Cited by 3 · see citing works
Threadingham, D., Obrecht, W., Lambert, J. M., Happ, M., Oppenheimer‐Stix, C., Dunn, J. R., Krüger, R., Brandt, H., Nentwig, W., Rooney, N., et al. (2000) · Ullmann's Encyclopedia of Industrial Chemistry · doi:10.1002/14356007.a23_239 · Cited by 3 · see citing works
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Elias, A. J., Reddy, N. D., & Ramakrishna, T. V. V. (1999) · Journal of Chemical Sciences · doi:10.1007/bf02870842 · Cited by 2 · see citing works
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Threadingham, D., Obrecht, W., Lambert, J. M., Happ, M., Oppenheimer‐Stix, C., Dunn, J. R., Krüger, R., Brandt, H., Nentwig, W., Rooney, N., et al. (2004) · Ullmann's Encyclopedia of Industrial Chemistry · doi:10.1002/14356007.a23_239.pub4 · Cited by 1 · see citing works
Synthesis of polyphosphate and polyphosphate ester having pendant amine salt groups
Wang, C., Iwami, D., Takayama, T., et al. (1998) · Reactive and Functional Polymers · doi:10.1016/s1381-5148(97)00167-3 · Cited by 1 · see citing works
Behera, N., Kumar, M. S., & Elias, A. J. (2007) · Inorganica Chimica Acta · doi:10.1016/j.ica.2007.10.010 · Cited by 1 · see citing works
Roy, A. K. (2009) · Kirk-Othmer Encyclopedia of Chemical Technology · doi:10.1002/0471238961.09141518181525.a01.pub2 · Cited by 1 · see citing works
Tailored Design of New Polyphosphazenes with Special Properties
Allcock, H. R. (1992) · Springer eBooks · doi:10.1007/978-3-642-77636-6_9 · Cited by 1 · see citing works
Self-citationOrganic/Inorganic Hybrid Polymers
Rehahn, M. (2013) · Materials Science and Technology · doi:10.1002/9783527603978.mst0232
Organic/Inorganic Hybrid Polymers
Rehahn, M. (1998) · doi:10.1002/9783527619313.ch10
Roy, A. K. (2000) · Kirk-Othmer Encyclopedia of Chemical Technology · doi:10.1002/0471238961.09141518181525.a01
Bourke, S. C., & Ian Manners, A. (2001) · Encyclopedia of Polymer Science and Technology · doi:10.1002/0471440264.pst165
Self-citationKoltzenburg, S., Maskos, M., & Nuyken, O. (2013) · Springer eBooks · doi:10.1007/978-3-642-34773-3_12
Self-citationOther Inorganic Polymers that Contain Phosphorus, Boron and Sulfur
(2005) · Springer eBooks · doi:10.1007/3-540-26215-6_5
Koltzenburg, S., Maskos, M., & Nuyken, O. (2024) · Springer eBooks · doi:10.1007/978-3-662-64601-4_12
Self-citation
- Authors
- Allcock, H. R., Coley, S. M., Manners, I., Nuyken, O., & Renner, G.
- Affiliations
- Pennsylvania State University (US)
- University of Bayreuth (DE)
- ORCID
- Allcock, Harry R.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1991-04
- Volume
- 24
- Issue
- 8
- Pages
- 2024-2028
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2088297981
- Cited by
- 53
- References
- 0
- Citations by year
- 2025: 1 · 2024: 1 · 2023: 1 · 2018: 1 · 2017: 3 · 2015: 2 · 2013: 4 · 2012: 2
- FWCI
- 3.18
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Synthesis and properties of polymers
- Keywords
- polyphosphazenes, polymer synthesis, thermal stability
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