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Cited by 59Block Copolymer Self-AssemblyPolymer crystallization and propertiesAdvanced Polymer Synthesis and Characterization

Evaluation of domain spacing scaling laws for semicrystalline diblock copolymers

Douzinas, Konstadinos C., Cohen, Robert E., Halasa, Adel F.·1991·Macromolecules
DOI 10.1021/ma00015a033
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Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEvaluation of domain spacing scaling laws for semicrystalline diblock copolymersKonstadinos C. Douzinas, Robert E. Cohen, and Adel F. HalasaCite this: Macromolecules 1991, 24, 15, 4457–4459Publication Date (Print):July 1, 1991Publication History Published online1 May 2002Published inissue 1 July 1991https://pubs.acs.org/doi/10.1021/ma00015a033https://doi.org/10.1021/ma00015a033research-articleACS PublicationsRequest reuse permissionsArticle Views274Altmetric-Citations58LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

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  • In medium segregated systems (medium χN values, T_ODT > Tc > Tg), the final morphology depends on the applied thermal procedure: if the sample is cooled from the melt very fast (quenching), the morphology of the melt is maintained; otherwise, the final morphology is governed by the crystallization process.

    “For these block copolymers the final morphology (i.e., the morphology of the solidified sample) depends on the applied thermal procedure: if the sample is cooled from the melt very fast, i.e., quenching, the morphology of the melt is maintained. Otherwise, the final morphology will be governed by the crystallization process [ 102 , 103 , 150-153 , 160-164 , 172 , 173 ].”

    From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [160]

  • In weakly segregated systems (low χN values, T_ODT > Tc > Tg), there is little morphological restriction for crystallization, allowing a break out from the ordered melt structure, so crystallization determines the final structure, usually forming crystalline lamellae and erasing the previous melt structure.

    “In this case, there is little morphological restriction for the crystallization process, which allows a break out from the ordered melt structure, therefore the crystallization determines the final structure, usually crystalline lamellae are formed, erasing the previous structure of the melt [ 102 , 103 , 109 , 121 , 125 , 150-153 , 160-171 ].”

    From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [160]

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Authors
Douzinas, K. C., Cohen, R. E., & Halasa, A. F.
ORCID
Cohen, Robert E.
Venue
Macromolecules
Publisher
American Chemical Society (ACS)
Published
1991-07
Volume
24
Issue
15
Pages
4457-4459
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
DOI
10.1021/ma00015a033
OpenAlex
W2073281596
Cited by
59
References
0
Citations by year
2021: 1 · 2020: 2 · 2017: 4 · 2016: 3 · 2015: 1 · 2014: 2 · 2013: 1
FWCI
3.00
Type
journal article
Language
en
Open access
closed
Locations
Macromolecules (publishedVersion)
Topics
  • Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords
domain spacing, scaling laws, block copolymer self-assembly, lamellar phase, polymer microphase separation

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