Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 724

The DOI matches its Crossref record.

Dynamics of reversible networks

Leibler, Ludwik, Rubinstein, Michael, Colby, Ralph H.·1991·Macromolecules
DOI 10.1021/ma00016a034
Open this paper in CoChat — free account

Abstract

ABSTRACT We present a model for dynamics of entangled networks made up of linear chains with many temporary cross-links. At times shorter than the lifetime of a cross-link such networks behave as elastic rubbers (gels). On longer time scales the successive breaking of only a few cross-links allows the chain to diffuse along its confining tube. The motion of a chain in this hindered reptation model is controlled by the concentration and lifetime of tie points. We calculate the self-diffusion coefficient and discuss the stress relaxation in terms of molecular parameters, including the chain length, the number of cross-linking groups per chain, and the lifetime and probability of formation of cross-links. We find good agreement with recent experiments by Stadler et al. on model thermoplastic elastomers. 1.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1021/ma00016a034

Cites

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cited by

See all 724

Metadata

Authors
Leibler, L., Rubinstein, M., & Colby, R. H.
Venue
Macromolecules
Publisher
American Chemical Society (ACS)
Published
1991-08
Volume
24
Issue
16
Pages
4701-4707
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
DOI
10.1021/ma00016a034
OpenAlex
W2155409190
Cited by
724
References
0
FWCI
4.24
Type
journal article
Language
en
Open access
closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Dynamics of reversible networks. https://app.cochat.ai/papers/10.1021/ma00016a034
The paper
Leibler, L., Rubinstein, M., & Colby, R. H. (1991). Dynamics of reversible networks. Macromolecules. https://doi.org/10.1021/ma00016a034

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.