Dynamic covalent chemistry in polymer networks: a mechanistic perspective
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A selection of dynamic chemistries is highlighted, with a focus on the reaction mechanisms of molecular network rearrangements, and on how mechanistic profiles can be related to the mechanical and physicochemical properties of polymer materials.
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Existing strategies to create reprocessable thermosets have focused on dynamic covalent bond exchange, thermomechanical degradation, or wholesale replacement of network components with degradable versions.
“Existing strategies to create reprocessable thermosets have focused on dynamic covalent bond exchange, 3-8 thermomechanical degradation, 9 or wholesale replacement of network components with degradable versions. 10-13”
From Cleavable comonomers enable degradable, recyclable thermoset plastics (2020) · cites this paper as [5]
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Emerging applications of stimuli-responsive polymer materials
Stuart, M. A. C., Huck, W. T. S., Genzer, J., Müller, M., Ober, C. K., Stamm, M., Sukhorukov, G. B., Szleifer, I. G., Tsukruk, V. V., Urban, M. W., et al. (2010) · Nature Materials · doi:10.1038/nmat2614 · Cited by 5,720 · see citing works
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625 · see citing works
A Thermally Re-mendable Cross-Linked Polymeric Material
Chen, X., Dam, M. A., Ono, K., Mal, A., Shen, H., Nutt, S., Sheran, K., & Wudl, F. (2002) · Science · doi:10.1126/science.1065879 · Cited by 2,649 · see citing works
Vitrimers: permanent organic networks with glass-like fluidity
Denissen, W., Winne, J. M., & Prez, F. D. (2015) · Chemical Science · doi:10.1039/c5sc02223a · Cited by 1,810 · see citing works
Self-citationUsing the dynamic bond to access macroscopically responsive structurally dynamic polymers
Wojtecki, R. J., Meador, M. A., & Rowan, S. J. (2010) · Nature Materials · doi:10.1038/nmat2891 · Cited by 1,664 · see citing works
The Thiol-Michael Addition Click Reaction: A Powerful and Widely Used Tool in Materials Chemistry
Nair, D. P., Podgórski, M., Chatani, S., Gong, T., Xi, W., Fenoli, C. R., & Bowman, C. N. (2013) · Chemistry of Materials · doi:10.1021/cm402180t · Cited by 1,602 · see citing works
Self-Healing Polymers and Composites
Blaiszik, B. J., Kramer, S. L. B., Olugebefola, S. C., Moore, J. S., Sottos, N. R., & White, S. R. (2010) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-070909-104532 · Cited by 1,505 · see citing works
Recent advances in dynamic covalent chemistry
Jin, Y., Yu, C., Denman, R. J., & Zhang, W. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60044k · Cited by 1,490 · see citing works
High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis
Röttger, M., Domenech, T., van der Weegen, R., Breuillac, A., Nicolaÿ, R., & Leibler, L. (2017) · Science · doi:10.1126/science.aah5281 · Cited by 1,394 · see citing works
Self-citationCovalent adaptable networks: smart, reconfigurable and responsive network systems
Kloxin, C. J., & Bowman, C. N. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60046g · Cited by 1,380 · see citing works
Belowich, M. E., & Stoddart, J. F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15305j · Cited by 1,372 · see citing works
Catalytic Control of the Vitrimer Glass Transition
Capelot, M., Unterlass, M. M., Tournilhac, F., & Ludwik Leibler, B. (2012) · ACS Macro Letters · doi:10.1021/mz300239f · Cited by 1,217 · see citing works
Metal-Catalyzed Transesterification for Healing and Assembling of Thermosets
Capelot, M., Montarnal, D., Tournilhac, F., & Ludwik Leibler, B. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302894k · Cited by 1,206 · see citing works
Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
Kloxin, C. J., Scott, T. F., Adzima, B. J., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma902596s · Cited by 1,175 · see citing works
Denissen, W., Rivero, G., Nicolaÿ, R., Ludwik Leibler, B., Winne, J. M., & Prez, F. D. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201404553 · Cited by 1,130 · see citing works
Self-citationMalleable and Self-Healing Covalent Polymer Networks through Tunable Dynamic Boronic Ester Bonds
Cromwell, O. R., Chung, J., & Guan, Z. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03551 · Cited by 1,056 · see citing works
Dynamic Covalent Bonds in Polymeric Materials
Chakma, P., & Konkolewicz, D. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201813525 · Cited by 1,025 · see citing works
Dynamic Covalent Polymer Networks: from Old Chemistry to Modern Day Innovations
Zou, W., Dong, J., Luo, Y., Zhao, Q., & Xie, T. (2017) · Advanced Materials · doi:10.1002/adma.201606100 · Cited by 1,014 · see citing works
Self-Healing Materials Based on Disulfide Links
Canadell, J., Goossens, H., & Klumperman, B. (2011) · Macromolecules · doi:10.1021/ma2001492 · Cited by 1,012 · see citing works
Dynamic urea bond for the design of reversible and self-healing polymers
Ying, H., Zhang, Y., & Cheng, J. (2014) · Nature Communications · doi:10.1038/ncomms4218 · Cited by 987 · see citing works
Pascault, J., Sautereau, H. J., Jacques Verdu, C., & Williams, R. J. J. (2002) · CRC Press eBooks · doi:10.1201/9780203908402 · Cited by 963 · see citing works
Otera, J. (1993) · Chemical Reviews · doi:10.1021/cr00020a004 · Cited by 951 · see citing works
Catalyst-free room-temperature self-healing elastomers based on aromatic disulfide metathesis
Rekondo, A., Martín, R., de Luzuriaga, A. R., Cabañero, G., Grande, H. J., & Odriozola, I. (2013) · Materials Horizons · doi:10.1039/c3mh00061c · Cited by 907 · see citing works
Heat‐ or Water‐Driven Malleability in a Highly Recyclable Covalent Network Polymer
Taynton, P., Yu, K., Shoemaker, R. K., Jin, Y., Qi, H. J., & Zhang, W. (2014) · Advanced Materials · doi:10.1002/adma.201400317 · Cited by 890 · see citing works
Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Fortman, D. J., Brutman, J. P., Cramer, C. J., Hillmyer, M. A., & Dichtel, W. R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08084 · Cited by 811 · see citing works
Photoinduced Plasticity in Cross-Linked Polymers
Scott, T. F., Schneider, A. D., Cook, W. D., & Bowman, C. N. (2005) · Science · doi:10.1126/science.1110505 · Cited by 779 · see citing works
Dynamics of reversible networks
Ludwik Leibler, B., Rubinstein, M., & Colby, R. H. (1991) · Macromolecules · doi:10.1021/ma00016a034 · Cited by 733 · see citing works
DYNAMERS: dynamic polymers as self-healing materials
Roy, N., Bruchmann, B., & Lehn, J. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00194c · Cited by 718 · see citing works
Thermoreversible Gelation in Solutions of Associative Polymers. 1. Statics
Semenov, A. N., & Rubinstein, M. H. (1998) · Macromolecules · doi:10.1021/ma970616h · Cited by 670 · see citing works
Zheng, P., & McCarthy, T. J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2113257 · Cited by 624 · see citing works
Silyl Ether as a Robust and Thermally Stable Dynamic Covalent Motif for Malleable Polymer Design
Nishimura, Y., Chung, J., Muradyan, H., & Guan, Z. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b08826 · Cited by 587 · see citing works
Chemical control of the viscoelastic properties of vinylogous urethane vitrimers
Denissen, W., Droesbeke, M. A., Nicolaÿ, R., Ludwik Leibler, B., Winne, J. M., & Prez, F. D. (2017) · Nature Communications · doi:10.1038/ncomms14857 · Cited by 559 · see citing works
Self-citationDynamic covalent polymers: Reorganizable polymers with dynamic covalent bonds
Maeda, T., Otsuka, H., & Takahara, A. (2009) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.03.001 · Cited by 556 · see citing works
Obadia, M. M., Mudraboyina, B. P., Serghei, A., Montarnal, D., & Drockenmuller, É. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b02653 · Cited by 521 · see citing works
Covalent Adaptable Networks: Reversible Bond Structures Incorporated in Polymer Networks
Bowman, C. N., & Kloxin, C. J. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201200708 · Cited by 519 · see citing works
Thermoreversible Gelation in Solutions of Associating Polymers. 2. Linear Dynamics
Rubinstein, M. H., & Semenov, A. N. (1998) · Macromolecules · doi:10.1021/ma970617+ · Cited by 485 · see citing works
Self-healing and self-mendable polymers
Syrett, J. A., Becer, C. R., & Haddleton, D. M. (2010) · Polymer Chemistry · doi:10.1039/c0py00104j · Cited by 412 · see citing works
Self-Healing of Unentangled Polymer Networks with Reversible Bonds
Stukalin, E. B., Cai, L.-H., Kumar, N. A., Ludwik Leibler, B., & Rubinstein, M. (2013) · Macromolecules · doi:10.1021/ma401111n · Cited by 400 · see citing works
Reprocessable Acid-Degradable Polycarbonate Vitrimers
Snyder, R. L., Fortman, D. J., Hoe, G. X. D., Hillmyer, M. A., & Dichtel, W. R. (2018) · Macromolecules · doi:10.1021/acs.macromol.7b02299 · Cited by 391 · see citing works
Billiet, S., Bruycker, K. D., Driessen, F., et al. (2014) · Nature Chemistry · doi:10.1038/nchem.2023 · Cited by 356 · see citing works
Skene, W. G., & Lehn, J.-M. P. (2004) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0401885101 · Cited by 348 · see citing works
Azcune, I., & Odriozola, I. (2016) · European Polymer Journal · doi:10.1016/j.eurpolymj.2016.09.023 · Cited by 343 · see citing works
Delahaye, M., Winne, J. M., & Du Prez, F. E. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07269 · Cited by 334 · see citing works
Self-citationImbernon, L., Oikonomou, E. K., Norvez, S., & Ludwik Leibler, B. (2015) · Polymer Chemistry · doi:10.1039/c5py00459d · Cited by 331 · see citing works
Dynamics of associative polymers
Zhang, Z., Chen, Q., & Colby, R. H. (2018) · Soft Matter · doi:10.1039/c8sm00044a · Cited by 298 · see citing works
Room Temperature Dynamic Polymers Based on Diels–Alder Chemistry
Reutenauer, P., Buhler, E., Boul, P. J., Candau, S. J., & Lehn, J. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200802145 · Cited by 291 · see citing works
Poly(thioether) Vitrimers via Transalkylation of Trialkylsulfonium Salts
Hendriks, B., Waelkens, J., Winne, J. M., & Prez, F. E. D. (2017) · ACS Macro Letters · doi:10.1021/acsmacrolett.7b00494 · Cited by 290 · see citing works
Self-citationFluorinated Vitrimer Elastomers with a Dual Temperature Response
Guerre, M., Taplan, C., Nicolaÿ, R., Winne, J. M., & Prez, F. D. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b07094 · Cited by 285 · see citing works
Self-citationStress Relaxation Studies of the Viscoelastic Properties of Polymers
Tobolsky, A. V. (1956) · Journal of Applied Physics · doi:10.1063/1.1722465 · Cited by 239 · see citing works
Tuning the Viscosity Profile of Ionic Vitrimers Incorporating 1,2,3‐Triazolium Cross‐Links
Obadia, M. M., Jourdain, A., Cassagnau, P., Montarnal, D., & Drockenmuller, É. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201703258 · Cited by 227 · see citing works
Goussé, C., Gandini, A., & Hodge, P. (1998) · Macromolecules · doi:10.1021/ma9710141 · Cited by 226 · see citing works
Triazolinediones as Highly Enabling Synthetic Tools
Bruycker, K. D., Billiet, S., Houck, H. A., Chattopadhyay, S., Winne, J. M., & Prez, F. D. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00599 · Cited by 218 · see citing works
Self-citationRicarte, R. G., Tournilhac, F., & Ludwik Leibler, B. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b02144 · Cited by 210 · see citing works
Dynamic Thiol–Michael Chemistry for Thermoresponsive Rehealable and Malleable Networks
Zhang, B., Digby, Z. A., Flum, J. A., et al. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b01061 · Cited by 178 · see citing works
Chemical Stress-Relaxation of Polydimethylsiloxane Elastomers1
Osthoff, R. C., Bueche, A. M., & Grubb, W. T. (1954) · Journal of the American Chemical Society · doi:10.1021/ja01647a052 · Cited by 176 · see citing works
Coordination and catalysis of Zn 2+ in epoxy-based vitrimers
Demongeot, A., Mougnier, S., Okada, S., Soulié‐Ziakovic, C., & Tournilhac, F. (2016) · Polymer Chemistry · doi:10.1039/c6py00752j · Cited by 165 · see citing works
Substituent Effects on the Reversibility of Furan–Maleimide Cycloadditions
Boutelle, R. C., & Northrop, B. H. (2011) · The Journal of Organic Chemistry · doi:10.1021/jo201606z · Cited by 164 · see citing works
Bistable and photoswitchable states of matter
Worrell, B. T., McBride, M. K., Lyon, G. B., Cox, L. M., Wang, C., Mavila, S., Lim, C., Coley, H. M., Musgrave, C. B., Ding, Y., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-05300-7 · Cited by 164 · see citing works
Krenske, E. H., Petter, R. C., & Houk, K. N. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.6b02188 · Cited by 152 · see citing works
Inglis, A. J., Nebhani, L., Altintas, O., et al. (2010) · Macromolecules · doi:10.1021/ma100945b · Cited by 151 · see citing works
Reversible Diels−Alder Reactions for the Generation of Dynamic Combinatorial Libraries
Boul, P. J., Reutenauer, P., & Lehn, J. (2004) · Organic Letters · doi:10.1021/ol048065k · Cited by 148 · see citing works
Rolph, M. S., Markowska, A. L. J., Warriner, C. N., et al. (2016) · Polymer Chemistry · doi:10.1039/c6py01776b · Cited by 130 · see citing works
Worrell, B. T., Mavila, S., Wang, C., Kontour, T. M., Lim, C., McBride, M. K., Musgrave, C. B., Shoemaker, R. L., & Bowman, C. N. (2018) · Polymer Chemistry · doi:10.1039/c8py01031e · Cited by 123 · see citing works
Patchy Particle Model for Vitrimers
Smallenburg, F., Ludwik Leibler, B., & Sciortino, F. (2013) · Physical Review Letters · doi:10.1103/physrevlett.111.188002 · Cited by 118 · see citing works
Epoxy Vitrimers: The Effect of Transesterification Reactions on the Network Structure
Altuna, F. I., Hoppe, C. E., & Williams, R. J. J. (2018) · Polymers · doi:10.3390/polym10010043 · Cited by 118 · see citing works
Dynamics of Vitrimers: Defects as a Highway to Stress Relaxation
Ciarella, S., Sciortino, F., & Ellenbroek, W. G. (2018) · Physical Review Letters · doi:10.1103/physrevlett.121.058003 · Cited by 115 · see citing works
Fast Healing of Polyurethane Thermosets Using Reversible Triazolinedione Chemistry and Shape-Memory
Herck, N. V., & Prez, F. D. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b00368 · Cited by 109 · see citing works
Complex formation in polymer-ion solution. 1. Polymer concentration effects
Pezron, E., Ludwik Leibler, B., Ricard, A., et al. (1989) · Macromolecules · doi:10.1021/ma00193a030 · Cited by 97 · see citing works
Reversible gel formation induced by ion complexation. 2. Phase diagrams
Pezron, E., Ludwik Leibler, B., Ricard, A., et al. (1988) · Macromolecules · doi:10.1021/ma00182a046 · Cited by 90 · see citing works
Stress-Time-Temperature Relations in Polysulfide Rubbers
Stern, M. D., & Tobolsky, A. V. (1946) · The Journal of Chemical Physics · doi:10.1063/1.1724110 · Cited by 88 · see citing works
Dynamics and the Regiochemistry of Nitration of Toluene
Nieves‐Quinones, Y., & Singleton, D. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07328 · Cited by 85 · see citing works
Stress Relaxation by Addition−Fragmentation Chain Transfer in Highly Cross-Linked Thiol−Yne Networks
Park, H., Kloxin, C. J., Scott, T. F., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma1020209 · Cited by 83 · see citing works
Rheology of galactomannan‐borax gels
Pezron, E., Ricard, A., & Ludwik Leibler, B. (1990) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.1990.090281301 · Cited by 80 · see citing works
A real recycling loop of sulfur-cured rubber through transalkylation exchange of C–S bonds
Tang, Z., Liu, Y., Huang, Q., Zhao, J., Guo, B., & Zhang, L. (2018) · Green Chemistry · doi:10.1039/c8gc02932f · Cited by 72 · see citing works
Chakma, P., Digby, Z. A., Shulman, M. P., et al. (2019) · ACS Macro Letters · doi:10.1021/acsmacrolett.8b00819 · Cited by 69 · see citing works
The First Method for Protection−Deprotection of the Indole 2,3-π Bond
Baran, P. S., Guerrero, C. A., & Corey, E. J. (2003) · Organic Letters · doi:10.1021/ol034634x · Cited by 68 · see citing works
Self‐Healing Polymer Networks Based on Reversible Michael Addition Reactions
Kuhl, N., Geitner, R., Bose, R. K., et al. (2016) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201600353 · Cited by 65 · see citing works
THE THERMAL REVERSIBILITY OF THE MICHAEL REACTION: IV. THIOL ADDUCTS
Allen, C. F. H., Fournier, J. O., & Humphlett, W. J. (1964) · Canadian Journal of Chemistry · doi:10.1139/v64-383 · Cited by 64 · see citing works
Design of a thermally controlled sequence of triazolinedione-based click and transclick reactions
Houck, H. A., Bruycker, K. D., Billiet, S., et al. (2017) · Chemical Science · doi:10.1039/c7sc00119c · Cited by 56 · see citing works
Probing the mechanism of thermally driven thiol-Michael dynamic covalent chemistry
Zhang, B., Chakma, P., Shulman, M. P., et al. (2018) · Organic & Biomolecular Chemistry · doi:10.1039/c8ob00397a · Cited by 56 · see citing works
Harnessing entropy to direct the bonding/debonding of polymer systems based on reversible chemistry
Guimard, N. K., Ho, J., Brandt, J., et al. (2013) · Chemical Science · doi:10.1039/c3sc50642h · Cited by 55 · see citing works
New material: vitrimers promise to impact composites
Kissounko, D. A., Taynton, P., & Kaffer, C. (2017) · Reinforced Plastics · doi:10.1016/j.repl.2017.06.084 · Cited by 44 · see citing works
Freitas, L. D. L., Auschra, C., Abetz, V., et al. (1991) · Colloid & Polymer Science · doi:10.1007/bf00659910 · Cited by 30 · see citing works
Cationic polymerization of cyclic sulfides
Goethals, E. J. (1974) · Die Makromolekulare Chemie · doi:10.1002/macp.1974.021750414 · Cited by 27 · see citing works
Stadler, R. (1988) · Macromolecules · doi:10.1021/ma00179a025 · Cited by 27 · see citing works
Stress-Time-Temperature Relations in Polysulfide Rubbers
Stern, M., & Tobolsky, A. V. (1946) · Rubber Chemistry and Technology · doi:10.5254/1.3543255 · Cited by 24 · see citing works
Flagged first, then by citations
Research works printed but not linked: 2
- M. E. Belowich and J. F. Stoddart, Dynamic imine chem- istry, Chem. Soc. Rev., 2012, 41(6), 2003-2024.
- E. Pezron, L. Leibler, A. Ricard and R. Audebert, Reversible gel formation induced by ion complexation. 2. Phase dia- grams, Macromolecules, 1988, 21(4), 1126-1131.
Cited by
Sorted by citations
Bio-based polymers with performance-advantaged properties
Cywar, R. M., Rorrer, N. A., Hoyt, C. B., Beckham, G. T., & Chen, E. Y.-X. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00363-3 · Cited by 811 · see citing works
Cleavable comonomers enable degradable, recyclable thermoset plastics
Shieh, P., Zhang, W., Husted, K. E. L., Kristufek, S. L., Xiong, B., Lundberg, D. J., Lem, J., Veysset, D., Sun, Y., Nelson, K. A., et al. (2020) · Nature · doi:10.1038/s41586-020-2495-2 · Cited by 498 · see citing works
- Authors
- Winne, J. M., Leibler, L., & Du Prez, F. E.
- Affiliations
- Ghent University (BE)
- UMR Gulliver 7083 CNRS
- Polymer Chemistry Research Group and Laboratory for Organic Synthesis
- Corresponding author
- Winne, Johan M.
- Venue
- Polymer Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2019
- Volume
- 10
- Issue
- 45
- Pages
- 6091-6108
- ISSN
- 1759-9954 (ISSN-L)
- 1759-9962
- OpenAlex
- W2980513544
- Cited by
- 736
- References
- 86
- Citations by year
- 2026: 119 · 2025: 118 · 2024: 106 · 2023: 122 · 2022: 121 · 2021: 65 · 2020: 83 · 2019: 2
- FWCI
- 28.92
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Polymer Chemistry (publishedVersion, cc-by-nc)
- Ghent University Academic Bibliography (Ghent University) (publishedVersion, other-oa)
- Ghent University Academic Bibliography (Ghent University) (submittedVersion, cc-by-nc)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Chemistry › Organic Chemistry › Supramolecular Chemistry and Complexes
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- dynamic covalent chemistry, polymer networks, reaction mechanism, network rearrangement, mechanical properties, physicochemical properties
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