The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Diels−Alder Reactions with Novel Polymeric Dienes and Dienophiles: Synthesis of Reversibly Cross-Linked Elastomers
Abstract
Novel highly flexible copolymers bearing dienic or dienophilic moieties were prepared by either free radical copolymerization of hexyl acrylate and 2-furfuryl methacrylate or the chemical modification of siloxane copolymers with pendant primary propylamino functions. In addition, maleimides were synthesized from oligoether bis(amine)s and from the amino pendant groups of the polysiloxane. Diels−Alder reactions between these copolymers and difunctional complementary coupling agents produced cross-linked elastomers in high yields. The thermal reversible character of these networks was confirmed by applying retro-Diels−Alder reactions in the presence of appropriate trapping reagents which restored the initial linear polymers quantitatively.
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Cites
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Gandini, A. (1997) · Progress in Polymer Science · doi:10.1016/s0079-6700(97)00004-x · Cited by 668
Self-citationReversible gelation of polyoxazoline by means of Diels-Alder reaction
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Goussé, C., Gandini, A., & Hodge, P. (1998) · Macromolecules · doi:10.1021/ma9710141 · Cited by 226
Self-citationThermally reversible crosslinking of polystyrene via the furan–maleimide Diels–Alder reaction
Canary, S. A., & Stevens, M. P. (1992) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.1992.080300829 · Cited by 134
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Self-citationDiels–Alder polymerization of difurans with bismaleimides
Goussé, C., & Gandini, A. (1999) · Polymer International · Cited by 89
Self-citationStructure and Reactivity of Lithiated α-Amino Nitriles
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Covalent adaptable networks: smart, reconfigurable and responsive network systems
Kloxin, C. J., & Bowman, C. N. (2013) · Chem. Soc. Rev. · doi:10.1039/c3cs60046g · Cited by 1,370
Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
Kloxin, C. J., Scott, T. F., Adzima, B. J., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma902596s · Cited by 1,175
Dynamic Covalent Polymer Networks: from Old Chemistry to Modern Day Innovations
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Metadata
- Authors
- Gheneim, R., Perez-Berumen, C., & Gandini, A.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-08-08
- Volume
- 35
- Issue
- 19
- Pages
- 7246-7253
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1983596263
- Cited by
- 292
- References
- 9
- FWCI
- 4.16
- Type
- journal article
- Language
- en
- Open access
- closed
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