The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Origin of Inhibition Effects in the Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization of Methyl Acrylate
Abstract
The reversible addition fragmentation chain transfer (RAFT) bulk polymerization of a fast propagating monomer (methyl acrylate, MA) has been studied using 1-phenylethyl dithiobenzoate (1-PEDB) and 2-(2-cyanopropyl) dithiobenzoate (CPDB) as RAFT agents at 60 °C. Rate retardation with increasing initial RAFT agent concentrations is common to both 1-PEDB- and CPDB-mediated MA polymerizations and occurs in comparable magnitude. A pronounced inhibition period is observed in 1-PEDB-mediated MA polymerizations, whereas the corresponding CPDB-mediated polymerizations show considerably less inhibition. The cause for this inhibition may either be associated with the leaving group of the initial RAFT agent or with the slow fragmentation of the initial intermediate macroRAFT radical. The present experimental data suggest that slow fragmentation is the probable cause for inhibition. We conclude that the radical intermediate formed by addition of radicals to the initial RAFT agent is different in stability than the macroRAFT radical formed analogously from macroRAFT agent. The inhibition period is effectively reduced by the use of CPDB as the initial RAFT agent in methyl acrylate polymerizations.
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Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
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Cited by
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
Xu, J., Jung, K., Atme, A., Shanmugam, S., & Boyer, C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501745g · Cited by 990
Kinetics of living radical polymerization
Goto, A., & Fukuda, T. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.01.002 · Cited by 914
Mechanism and kinetics of dithiobenzoate‐mediated RAFT polymerization. I. The current situation
Barner‐Kowollik, C., Buback, M., Charleux, B., Coote, M. L., Drache, M., Fukuda, T., Goto, A., Klumperman, B., Lowe, A. B., Mcleary, J. B., et al. (2006) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.21589 · Cited by 455
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Metadata
- Authors
- Perrier, S., Barner-Kowollik, C., Quinn, J. F., Vana, P., & Davis, T. P.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-09-21
- Volume
- 35
- Issue
- 22
- Pages
- 8300-8306
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2010018976
- Cited by
- 350
- References
- 3
- FWCI
- 14.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Perrier, S., Barner-Kowollik, C., Quinn, J. F., Vana, P., & Davis, T. P. (2002). Origin of Inhibition Effects in the Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization of Methyl Acrylate. Macromolecules. https://doi.org/10.1021/ma0203445
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