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Evidence for the Shift of the Glass Transition near the Particles in Silica-Filled Elastomers
Open accessAbstract
Filled elastomers exhibit a complex dependence of their viscoelastic modulus as a function of both temperature and frequency. Otherwise, recent observations on thin polymer films have shown that their glass transition temperature depends on their thickness. On the basis of these recent results and on a recent model, we propose that the mechanical behavior of the filled elastomer is strongly influenced by a gradient of the glass transition temperature in the vicinity of the particles. This allows us to suggest a specific temperature−frequency superposition law for filled rubbers. This law seems to apply very successfully on two systems with different dispersion qualities, revealing the existence of a glass transition temperature gradient in the vicinity of the particles.
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Citations
Cited by
Polymer/Silica Nanocomposites: Preparation, Characterization, Properties, and Applications
Zou, H., Wu, S., & Shen, J. (2008) · Chemical Reviews · doi:10.1021/cr068035q · Cited by 2,121
Robertson, C. G., Lin, C. J., Rackaitis, M., & Roland, C. M. (2008) · Macromolecules · doi:10.1021/ma7022364 · Cited by 316
Contact Aggregation, Bridging, and Steric Stabilization in Dense Polymer−Particle Mixtures
Hooper, J. B., & Schweizer, K. S. (2005) · Macromolecules · doi:10.1021/ma051318k · Cited by 295
Merabia, S., Sotta, P., & Long, D. R. (2008) · Macromolecules · doi:10.1021/ma8014728 · Cited by 284
Self-citationJouault, N., Vallat, P., Dalmas, F., Said, S., Jestin, J., & Boué, F. (2009) · Macromolecules · doi:10.1021/ma801908u · Cited by 278
Low-field NMR investigations of nanocomposites: Polymer dynamics and network effects
Papon, A., Saalwächter, K., Schäler, K., Guy, L., Lequeux, F., & Montes, H. (2011) · Macromolecules · doi:10.1021/ma102486x · Cited by 267
Self-citationMontes, H., Lequeux, F., & Berriot, J. (2003) · Macromolecules · doi:10.1021/ma0344590 · Cited by 189
Self-citationEffect of silica nanoparticles on the local segmental dynamics in poly (vinyl acetate)
Bogoslovov, R. B., Roland, C. M., Ellis, A. R., Randall, A. M., & Robertson, C. G. (2008) · Macromolecules · doi:10.1021/ma702372a · Cited by 176
Metadata
- Authors
- Berriot, J., Montes, H., Lequeux, F., Long, D., & Sotta, P.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-11-07
- Volume
- 35
- Issue
- 26
- Pages
- 9756-9762
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1977225912
- Cited by
- 438
- References
- 0
- FWCI
- 3.74
- Type
- journal article
- Language
- en
- Open access
- green
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
