The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
In-Situ Studies of Structure Development during Deformation of a Segmented Poly(urethane−urea) Elastomer
Abstract
The structural development of a segmented poly(urethane−urea) (PUU) elastomer containing a low concentration of hard segment during deformation was studied by simultaneous mechanical and optical measurements (rheooptical techniques). Specifically, in-situ wide-angle X-ray diffraction and small-angle X-ray scattering using synchrotron radiation and time-resolved Fourier transform infrared spectroscopy were applied to investigate the segmental orientation of PUU chains during cyclic elongation and recovery. Formation of two different domain microstructures is characterized with changes in strain. These microstructures consist of lamellar hard domains and highly stressed nanofibrils consisting of alternating hard and crystalline soft domains. By comparing the X-ray scattering and vibrational spectroscopic data, a morphological model of hard- and soft-segment microphase separation, orientation, and strain-induced crystallization in the soft segments was obtained.
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Cites
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Self-citationProperties of polyether-polyurethane block copolymers: effects of hard segment length distribution
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Degradation and stabilization of polyurethane elastomers
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Electrospun fine-textured scaffolds for heart tissue constructs
Zong, X., Bien, H., Chung, C.-Y., Yin, L., Fang, D., Hsiao, B. S., Chu, B., & Entcheva, E. (2005) · Biomaterials · doi:10.1016/j.biomaterials.2005.01.052 · Cited by 641
Self-citationHigh-performance elastomeric nanocomposites via solvent-exchange processing
Liff, S. M., Kumar, N., & McKinley, G. H. (2007) · Nature Materials · doi:10.1038/nmat1798 · Cited by 342
The structure, microphase-separated morphology, and property of polyurethanes and polyureas
He, Y., Xie, D., & Zhang, X. (2014) · Journal of Materials Science · doi:10.1007/s10853-014-8458-y · Cited by 289
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Metadata
- Authors
- Yeh, F., Hsiao, B. S., Sauer, B. B., Michel, S., & Siesler, H. W.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-02-27
- Volume
- 36
- Issue
- 6
- Pages
- 1940-1954
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1978759509
- Cited by
- 278
- References
- 17
- FWCI
- 5.22
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yeh, F., Hsiao, B. S., Sauer, B. B., Michel, S., & Siesler, H. W. (2003). In-Situ Studies of Structure Development during Deformation of a Segmented Poly(urethane−urea) Elastomer. Macromolecules. https://doi.org/10.1021/ma0214456
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
