The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Activator Generated by Electron Transfer for Atom Transfer Radical Polymerization
Abstract
A novel procedure was developed for activation of an oxidatively stable catalyst complex added to an atom transfer radical polymerization (ATRP). Tin(II) 2-ethylhexanoate (Sn(EH) 2 ) was used as a reducing agent of various Cu(II) complexes in ATRP of various monomers initiated by alkyl halides. This approach further improves a simultaneous normal and reverse initiation (SR&NI) by eliminating free radical initiators for the activation of the higher oxidation state catalyst complex. As a result, “activator generated by electron transfer” (AGET) ATRP allows the preparation of pure block copolymers. Several combinations of monomer/catalyst complex precursor were studied, including styrene/CuCl 2 /dNbpy, octadecyl methacrylate/CuCl 2 /dNbipy, methyl methacrylate/CuCl 2 /PMDETA, n -butyl acrylate/CuBr 2 /PMDETA, and methyl acrylate/CuCl 2 /Me 6 TREN. Polymerization proceeded in a controlled way for all systems, producing well-defined polymers with controlled degree of polymerization and narrow molecular weight distribution, demonstrating the robust nature of AGET ATRP. Additionally, Sn(EH) 2 was used simultaneously as a reducing agent for ATRP of octadecyl methacrylate and a catalyst for ring-opening polymerization (ROP) of ε-caprolactone, allowing direct synthesis of the corresponding block copolymer.
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Citations
Cites
Atom Transfer Radical Polymerization
Matyjaszewski, K., & Xia, J. (2001) · Chemical Reviews · doi:10.1021/cr940534g · Cited by 7,654
Self-citationMetal-Catalyzed Living Radical Polymerization
Kamigaito, M., Ando, T., & Sawamoto, M. (2001) · Chemical Reviews · doi:10.1021/cr9901182 · Cited by 3,275
Handbook of Radical Polymerization
(2002) · Wiley eBooks · doi:10.1002/0471220450 · Cited by 1,595
Polymers with Complex Architecture by Living Anionic Polymerization
Hadjichristidis, N., Pitsikalis, M., Pispas, S., & Iatrou, H. (2001) · Chemical Reviews · doi:10.1021/cr9901337 · Cited by 1,330
Kinetics of living radical polymerization
Goto, A., & Fukuda, T. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.01.002 · Cited by 914
Matyjaszewski, K., Patten, T. E., & Xia, J. (1997) · Journal of the American Chemical Society · doi:10.1021/ja963361g · Cited by 891
Self-citationSynthesis of Polymer Brushes Using Atom Transfer Radical Polymerization
Pyun, J., Kowalewski, T., & Matyjaszewski, K. (2003) · Macromolecular Rapid Communications · doi:10.1002/marc.200300078 · Cited by 686
Self-citationApplication of ionic liquids as solvents for polymerization processes
Kubisa, P. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2003.10.002 · Cited by 609
Adaptive and responsive surfaces through controlled reorganization of interfacial polymer layers
Luzinov, I., Minko, S., & Tsukruk, V. V. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.03.001 · Cited by 556
The Synthesis of Densely Grafted Copolymers by Atom Transfer Radical Polymerization
Beers, K. L., Gaynor, S. G., Matyjaszewski, K., Sheiko, S. S., & Möller, M. (1998) · Macromolecules · doi:10.1021/ma981402i · Cited by 550
Self-citationSynthesis of Branched and Hyperbranched Polystyrenes
Gaynor, S. G., Edelman, S., & Matyjaszewski, K. (1996) · Macromolecules · doi:10.1021/ma9513877 · Cited by 480
Self-citationGradient copolymers by atom transfer radical copolymerization
Matyjaszewski, K., Ziegler, M. J., Arehart, S. V., Greszta, D., & Pakula, T. (2000) · Journal of Physical Organic Chemistry · doi:10.1002/1099-1395(200012)13:12<775::aid-poc314>3.0.co;2-d · Cited by 424
Self-citationAtom Transfer Radical Polymerization of (Meth)acrylamides
Teodorescu, M., & Matyjaszewski, K. (1999) · Macromolecules · doi:10.1021/ma990175x · Cited by 348
Self-citationAdvances in Controlled/Living Radical Polymerization
(2003) · ACS Symposium Series · doi:10.1021/bk-2003-0854 · Cited by 345
Atom Transfer Radical Polymerization of 2-Hydroxyethyl Methacrylate
Beers, K. L., Boo, S., Gaynor, S. G., & Matyjaszewski, K. (1999) · Macromolecules · doi:10.1021/ma990176p · Cited by 288
Self-citationNew polymeric architectures with (meth)acrylic acid segments
Mori, H., & Müller, A. H. E. (2003) · Progress in Polymer Science · doi:10.1016/s0079-6700(03)00076-5 · Cited by 277
Nanostructured Carbon Arrays from Block Copolymers of Polyacrylonitrile
Kowalewski, T., Tsarevsky, N. V., & Matyjaszewski, K. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0178970 · Cited by 264
Self-citationCatalyst separation in atom transfer radical polymerization
SHEN, Y., TANG, H., & DING, S. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.08.002 · Cited by 239
Simultaneous Reverse and Normal Initiation in Atom Transfer Radical Polymerization
Gromada, J., & Matyjaszewski, K. (2001) · Macromolecules · doi:10.1021/ma010864k · Cited by 222
Self-citationPossibility of Living Radical Polymerization of Vinyl Acetate Catalyzed by Iron(I) Complex
Wakioka, M., Baek, K., Ando, T., Kamigaito, M., & Sawamoto, M. (2001) · Macromolecules · doi:10.1021/ma0115444 · Cited by 209
Matyjaszewski, K. (2003) · Polymer International · doi:10.1002/pi.1339 · Cited by 187
Self-citationKinetic Investigation of the Atom Transfer Radical Polymerization of Methyl Acrylate
Davis, K. A., Paik, H., & Matyjaszewski, K. A. (1999) · Macromolecules · doi:10.1021/ma9815051 · Cited by 167
Self-citationSynthesis and ATRP Activity of New TREN‐Based Ligands
Gromada, J., Spanswick, J., & Matyjaszewski, K. A. (2004) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200300082 · Cited by 56
Self-citation
Cited by
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Self-citationBarbey, R., Lavanant, L., Paripovic, D., Schüwer, N., Sugnaux, C., Tugulu, S., & Klok, H.-A. (2009) · Chemical Reviews · doi:10.1021/cr900045a · Cited by 1,753
Ouchi, M., Terashima, T., & Sawamoto, M. (2009) · Chemical Reviews · doi:10.1021/cr900234b · Cited by 1,257
Marrying click chemistry with polymerization: expanding the scope of polymeric materials
Golas, P. L., & Matyjaszewski, K. (2010) · Chem. Soc. Rev. · doi:10.1039/b901978m · Cited by 863
Self-citationAtrp in the design of functional materials for biomedical applications
Siegwart, D. J., Oh, J. K., & Matyjaszewski, K. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.08.001 · Cited by 613
Self-citation
Metadata
- Authors
- Jakubowski, W., & Matyjaszewski, K.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-04-21
- Volume
- 38
- Issue
- 10
- Pages
- 4139-4146
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2030714364
- Cited by
- 555
- References
- 23
- FWCI
- 14.69
- Type
- journal article
- Language
- en
- Open access
- closed
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